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通过在聚酯纤维织物上原位合成类花椰菜状氧化铜纳米粒子,实现其光催化和生物催化活性以及紫外线防护性能。

Photo and biocatalytic activities along with UV protection properties on polyester fabric through green in-situ synthesis of cauliflower-like CuO nanoparticles.

机构信息

Department of Textile Engineering, Amirkabir University of Technology, Functional Fibrous Structures & Environmental Enhancement (FFSEE), Tehran, Iran.

Department of Textile Engineering, Amirkabir University of Technology, Functional Fibrous Structures & Environmental Enhancement (FFSEE), Amirkabir Nanotechnoloy Research Institute (ANTRI), Tehran, Iran..

出版信息

J Photochem Photobiol B. 2017 Nov;176:100-111. doi: 10.1016/j.jphotobiol.2017.09.021. Epub 2017 Sep 27.

Abstract

In this paper, a facile environmentally friendly method is introduced for in-situ synthesis and fabrication of cauliflower-like CuO nanoparticles on the polyester fabric to produce photo and biocatalytic activities with UV protection properties on polyester fabric. The ash of burnt leaves and stems of Seidlitzia rosmarinus plant called Keliab was used as a natural and nontoxic alkaline source for simultaneous synthesis of CuO nanoparticles and surface modification of polyester without using any other compounds. The images of field-emission scanning electron microscopy, patterns of energy-dispersive spectroscopy, UV-visible spectrum and X-ray diffraction confirmed successful synthesis and loading of CuO nanoparticles on the polyester fabric. The treated fabrics showed very good antibacterial activities toward two pathogen bacteria including Staphylococcus aureus as a Gram-positive and Escherichia coli as a Gram-negative bacteria with no adverse effects on human dermal fibroblasts based on MTT test. The treated fabrics confirmed significant photocatalytic activity for degradation of methylene blue under sunlight, self-cleaning properties under UV light and also UV protection properties. Further a colorant effect along with an improvement in the wettability and mechanical properties of the treated fabrics were indicated. Overall, this method can be applied as a clean route for producing photo and bio active textiles protecting against UV irradiation.

摘要

本文介绍了一种简便的环保方法,用于在聚酯纤维织物上原位合成并制备类似菜花的氧化铜纳米粒子,以在聚酯纤维织物上产生光催化和生物催化活性以及具有紫外线防护性能。使用 Seidlitzia rosmarinus 植物(称为 Keliab)的燃烧后的叶和茎灰作为天然无毒的碱性源,同时合成氧化铜纳米粒子并对聚酯进行表面改性,而无需使用任何其他化合物。场发射扫描电子显微镜的图像、能谱图、紫外可见光谱和 X 射线衍射证实了氧化铜纳米粒子在聚酯纤维上的成功合成和负载。处理过的织物对两种病原菌(包括革兰氏阳性的金黄色葡萄球菌和革兰氏阴性的大肠杆菌)表现出非常好的抗菌活性,基于 MTT 测试对人体成纤维细胞没有不良影响。处理过的织物在阳光下对亚甲基蓝的光催化降解具有显著的催化活性,在紫外光下具有自清洁性能,并且具有紫外线防护性能。此外,还表明处理过的织物具有颜色效果,以及润湿性和机械性能的提高。总的来说,这种方法可以作为一种清洁的途径,用于生产具有光催化和生物活性的纺织品,以防止紫外线辐射。

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