用于水环境污染光催化修复的纳米级宽带半导体。
Nanoscale wide-band semiconductors for photocatalytic remediation of aquatic pollution.
机构信息
ICAR-Indian Institute of Agricultural Biotechnology (IIAB), IINRG Campus, Namkum, Ranchi, Jharkhand, 834010, India.
Department of Molecular Biology & Bioinformatics, Tripura University (A Central University), Suryamaninagar, Agartala, Tripura, 799022, India.
出版信息
Environ Sci Pollut Res Int. 2017 Nov;24(33):25775-25797. doi: 10.1007/s11356-017-0252-3. Epub 2017 Oct 7.
Water pollution is a serious challenge to the public health. Among different forms of aquatic pollutants, chemical and biological agents create paramount threat to water quality when the safety standards are surpassed. There are many conventional remediatory strategies that are practiced such as resin-based exchanger and activated charcoal/carbon andreverse osmosis. Newer technologies using plants, microorganisms, genetic engineering, and enzyme-based approaches are also proposed for aquatic pollution management. However, the conventional technologies have shown impending inadequacies. On the other hand, new bio-based techniques have failed to exhibit reproducibility, wide specificity, and fidelity in field conditions. Hence, to solve these shortcomings, nanotechnology ushered a ray of hope by applying nanoscale zinc oxide (ZnO), titanium dioxide (TiO), and tungsten oxide (WO) particles for the remediation of water pollution. These nanophotocatalysts are active, cost-effective, quicker in action, and can be implemented at a larger scale. These nanoparticles are climate-independent, assist in complete mineralization of pollutants, and can act non-specifically against chemically and biologically based aquatic pollutants. Photocatalysis for environmental remediation depends on the availability of solar light. The mechanism of photocatalysis involves the formation of electron-hole pairs upon light irradiations at intensities higher than their band gap energies. In the present review, different methods of synthesis of nanoscale ZnO, TiO, and WO as well as their structural characterizations have been discussed. Photodegradation of organic pollutants through mentioned nanoparticles has been reviewed with recent advancements. Enhancing the efficacy of photocatalysis through doping of TiO and ZnO nanoparticles with non-metals, metals, and metal ions has also been documented in this report.
水污染是公共健康面临的严重挑战。在各种形式的水生污染物中,当超过安全标准时,化学和生物制剂对水质构成了最大的威胁。有许多常规的修复策略,如树脂基交换剂和活性炭/碳纤维反渗透。还提出了使用植物、微生物、基因工程和基于酶的方法等新技术来管理水污染。然而,传统技术已经显示出迫在眉睫的不足。另一方面,新的基于生物的技术未能在现场条件下表现出重现性、广泛的特异性和保真度。因此,为了解决这些缺点,纳米技术通过应用纳米氧化锌 (ZnO)、二氧化钛 (TiO) 和氧化钨 (WO) 颗粒来修复水污染,带来了一线希望。这些纳米光催化剂具有活性、成本效益高、作用速度快,并且可以在更大的规模上实施。这些纳米颗粒不受气候影响,有助于污染物的完全矿化,并且可以针对化学和生物基水生污染物非特异性地发挥作用。光催化用于环境修复取决于太阳光的可用性。光催化的机制涉及在高于其能带隙能量的光照射下形成电子-空穴对。在本综述中,讨论了合成纳米 ZnO、TiO 和 WO 的不同方法及其结构特性。综述了通过所述纳米颗粒光降解有机污染物的情况,并介绍了通过掺杂 TiO 和 ZnO 纳米颗粒来提高光催化效率的最新进展。掺杂非金属、金属和金属离子。