Laboratoire de Thermique Energétique et Procédés (EAD 1932), UPPA, ENSGTI, BP 7511, 64075 Pau Cedex, France.
Department of Chemical Engineering, Building 35, Clayton Campus, Monash University, Victoria 3800, Australia.
Water Res. 2018 Feb 1;129:66-82. doi: 10.1016/j.watres.2017.10.063. Epub 2017 Nov 11.
Electro-dewatering (EDW) is an alternative emerging and energy-efficient technology that provides improved liquid/solids separations in the dewatering of wastewater sludge. The EDW technology is not only an innovative dewatering method for significantly reducing the volume of wastewater sludge before re-utilization or disposal, but is also a promising emerging method which may potentially be used for decontamination purposes. In this study, the influence of the sludge properties (e.g. electrical conductivity, zeta potential, specific cake resistance, among others) on their mechanical and electrical behaviour in terms of dewaterability and electro-dewaterability, the applied current (current density from 20 to 80 A/m), and filter cloth position relative to the electrode was investigated. A two-sided filter press at lab-scale with moving anode was used, and the treatment performance of the EDW process on two different types of wastewater sludge (activated and digested) was thoroughly assessed from both an electrochemical viewpoint and in terms of the dewatering rate. The results showed that the conditioned digested sludge was more easily dewatered by mechanical dewatering (MDW) with 34-35% (w%) of dry solids content compared to 19-20% (w%) for the activated sludge, thanks to the lower content of both the microbial extracellular polymeric substances (EPS) and the volatile suspended solids fraction. For the EDW results, the electrical conductivity of the sludge was pivotal to the dryness of the final solids and therefore also to the dewatering kinetics. The results demonstrated that the activated sludge arrived at an equilibrium much faster (after approximately 3600 s) compared with digested sludge, thanks to its lower electrical conductivity (0.8 mS/cm) providing a greater voltage drop across the cathode and therefore more repulsion of the solids from the cathode leading to continuously high filtrate flowrate. Also the EDW performance was analysed by comparing the ratio of the filtrate volume collected at the anode to the volume collected at the cathode side. For digested sludge at 5 bar, 40 A/m different positions of the filter cloth were tested but these configurations barely impacted the EDW performance, despite having a significant impact on the energy requirements. At industrial scale, it would be useful to position the filter cloths at some distance from the electrodes, but this study shows that this benefit may be quickly outweighed by the loss in EDW energy efficiency.
电脱水(EDW)是一种新兴的节能技术,可改善废水污泥脱水过程中的液/固分离。EDW 技术不仅是一种创新的脱水方法,可显著减少再利用或处置前的废水污泥体积,而且还是一种很有前途的新兴方法,可能可用于去污目的。在这项研究中,研究了污泥性质(例如电导率、zeta 电位、比滤饼阻力等)对其机械和电气脱水性能和电脱水性能的影响,应用电流(20 至 80 A/m 的电流密度),以及相对于电极的滤布位置。使用实验室规模的双面压滤机和移动阳极,从电化学角度和脱水率方面彻底评估了 EDW 工艺对两种不同类型的废水污泥(活性污泥和消化污泥)的处理性能。结果表明,调理后的消化污泥通过机械脱水(MDW)更容易脱水,其干固体含量为 34-35%(w%),而活性污泥为 19-20%(w%),这得益于微生物胞外聚合物(EPS)和挥发性悬浮固体(VSS)含量均较低。对于 EDW 结果,污泥的电导率对于最终固体的干燥度以及脱水动力学至关重要。结果表明,活性污泥达到平衡的速度更快(大约 3600 秒后),这是由于其电导率较低(0.8 mS/cm),导致在阴极处的电压降更大,从而使固体从阴极受到更大的排斥,从而导致滤液流量持续较高。还通过比较收集在阳极处的滤液体积与收集在阴极侧的滤液体积的比值来分析 EDW 性能。对于消化污泥在 5 巴和 40 A/m 的情况下,测试了滤布的不同位置,但这些配置对 EDW 性能的影响很小,尽管对能源需求有重大影响。在工业规模下,将滤布放置在电极一定距离处会很有用,但本研究表明,EDW 能效的损失可能很快超过此优势。