恶唑啉衍生物的束内电子轰击与B/E联动扫描质谱联用用于长链不饱和脂肪酸结构测定
Combined in-beam electron impact-B/E-linked scan mass spectrometry of oxazoline derivatives for the structure determination of long-chain unsaturated fatty acids.
作者信息
Yang Y M, Zhang J Y, Huang Z H
机构信息
Laboratory of Mass Spectrometry, Shanghai Institute of Materia Medica, Chinese Academy of Sciences.
出版信息
J Lipid Res. 1989 Jan;30(1):127-33.
PMID:2918247
Abstract
Long-chain unsaturated fatty acids (UFA) having up to six double bonds are derivatized to 2-substituted 4,4-dimethyloxazolines (DMOX) and then analyzed by combined in-beam electron impact (IBEI)-B/E-linked scan mass spectrometry. This technique provides highly characteristic mass spectra and may serve as an auxiliary means for direct structure determination of individual UFA in mixtures.
摘要
具有多达六个双键的长链不饱和脂肪酸（UFA）被衍生化为2-取代的4,4-二甲基恶唑啉（DMOX），然后通过束内电子轰击（IBEI）-B/E联动扫描质谱联用进行分析。该技术提供了高度特征性的质谱图，可作为直接确定混合物中单个UFA结构的辅助手段。
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