Assael M J, Papalas T B, Huber M L
Laboratory of Thermophysical Properties and Environmental Processes, Chemical Engineering Department, Aristotle University, Thessaloniki 54636, Greece.
Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305, USA.
J Phys Chem Ref Data. 2017 Sep;46(3). doi: 10.1063/1.4996885.
This paper presents new wide-ranging correlations for the viscosity and thermal conductivity of -undecane based on critically evaluated experimental data. The correlations are designed to be used with a recently published equation of state that is valid from the triple point to 700 K, at pressures up to 500 MPa, with densities below 776.86 kg m. The estimated uncertainty for the dilute-gas viscosity is 2.4%, and the estimated uncertainty for viscosity in the liquid phase for pressures up to 60 MPa over the temperature range 260 K to 520 K is 5%. The estimated uncertainty is 3% for the thermal conductivity of the low-density gas, and 3% for the liquid over the temperature range from 284 K to 677 K at pressures up to 400 MPa. Both correlations behave in a physically reasonable manner when extrapolated to the full range of the equation of state, however care should be taken when using the correlations outside of the validated range. The uncertainties will be larger outside of the validated range, and also in the critical region.
本文基于严格评估的实验数据,给出了关于正十一烷粘度和热导率的新的广泛关联式。这些关联式旨在与最近发表的状态方程一起使用,该状态方程在三相点至700K、压力高达500MPa、密度低于776.86kg/m³的条件下有效。稀气体粘度的估计不确定度为2.4%,在260K至520K温度范围内、压力高达60MPa时液相粘度的估计不确定度为5%。低密度气体热导率的估计不确定度为3%,在压力高达400MPa、温度范围为284K至677K时液体热导率的估计不确定度为3%。当外推到状态方程的整个范围时,两个关联式的表现都符合物理常理,但是在验证范围之外使用这些关联式时应谨慎。在验证范围之外以及临界区域,不确定度会更大。