College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, P.R. China.
Institute of Physical Chemistry and Electrochemistry, Leibniz Universität Hannover, Callinstraße 3A, 30167, Hannover, Germany.
Angew Chem Int Ed Engl. 2018 Apr 3;57(15):4083-4087. doi: 10.1002/anie.201712816. Epub 2018 Mar 8.
Covalent organic frameworks (COFs) are attractive candidates for advanced water-treatment membranes owing to their high porosity and well-organized channel structures. Herein, the continuous two-dimensional imine-linked COF-LZU1 membrane with a thickness of only 400 nm was prepared on alumina tubes by in situ solvothermal synthesis. The membrane shows excellent water permeance (ca. 760 L m h MPa ) and favorable rejection rates exceeding 90 % for water-soluble dyes larger than 1.2 nm. The water permeance through the COF-LZU1 membrane is much higher than that of most membranes with similar rejection rates. Long-time operation demonstrates the outstanding stability of the COF-LZU1 membrane. As the membrane has no selectivity for hydrated salt ions (selectivity <12 %), it is also suitable for the purification of dye products from saline solutions. The excellent performance and the outstanding water stability render the COF-LZU1 membrane an interesting system for water purification.
共价有机框架(COFs)因其高孔隙率和组织良好的通道结构,是先进水处理膜的有吸引力的候选材料。本文通过原位溶剂热合成,在氧化铝管上制备了厚度仅为 400nm 的连续二维亚胺键合 COF-LZU1 膜。该膜表现出优异的水透过率(约 760Lm h MPa)和对大于 1.2nm 的水溶性染料超过 90%的良好截留率。COF-LZU1 膜的水透过率远高于具有类似截留率的大多数膜。长时间运行证明了 COF-LZU1 膜的出色稳定性。由于该膜对水合盐离子没有选择性(选择性<12%),因此也适用于从盐溶液中纯化染料产品。优异的性能和出色的水稳定性使 COF-LZU1 膜成为水净化的有趣系统。