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用于波罗的海琥珀(琥珀)表征的中红外光谱法。

Mid-infrared spectroscopy for characterization of Baltic amber (succinite).

作者信息

Wagner-Wysiecka Ewa

机构信息

Gdansk University of Technology, Faculty of Chemistry, Narutowicza 11/12, 80-233 Gdańsk, Poland; International Amber Association, Warzywnicza 1, 80-838 Gdańsk, Poland.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2018 May 5;196:418-431. doi: 10.1016/j.saa.2018.02.053. Epub 2018 Feb 21.

Abstract

Natural Baltic amber (succinite) is the most appreciated fossil resin of the rich cultural traditions dating back to prehistoric times. Its unequivocal identification is extremely important in many branches of science and trades including archeology, paleontology, chemistry and finally mineralogical and gemological societies. Current methods of modification of natural succinite are more and more sophisticated making the identification of natural Baltic amber often challenging. In article the systematic analytical approach for identification of natural and modified under different conditions succinite, using mid-infrared spectroscopy (transmission, Drifts and ATR techniques) is presented. The correlation between spectral characteristics and properties of succinite is discussed pointing that the understanding of the nature of changes is the key of identification of this precious material.

摘要

天然波罗的海琥珀(琥珀)是最受珍视的化石树脂,其丰富的文化传统可追溯到史前时代。在包括考古学、古生物学、化学以及最终的矿物学和宝石学协会在内的许多科学和贸易领域,对其进行明确鉴定极为重要。目前天然琥珀的改性方法越来越复杂,这使得天然波罗的海琥珀的鉴定常常具有挑战性。本文介绍了一种系统的分析方法,用于使用中红外光谱(透射、漫反射和衰减全反射技术)鉴定天然琥珀以及在不同条件下改性的琥珀。文中讨论了琥珀光谱特征与其性质之间的相关性,指出对变化本质的理解是鉴定这种珍贵材料的关键。

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