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铂/氮掺杂碳/碳布:一种用于CO电化学还原和羧化反应的高效双功能催化剂。

Platinum/nitrogen-doped carbon/carbon cloth: a bifunctional catalyst for the electrochemical reduction and carboxylation of CO with excellent efficiency.

作者信息

Yang Heng-Pan, Lin Qing, Zhang Han-Wen, Li Guo-Dong, Fan Liang-Dong, Chai Xiao-Yan, Zhang Qian-Ling, Liu Jian-Hong, He Chuan-Xin

机构信息

Department of Chemistry, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China.

出版信息

Chem Commun (Camb). 2018 Apr 19;54(33):4108-4111. doi: 10.1039/c8cc00969d.

Abstract

A novel Pt-NP@NCNF@CC composite was prepared by the electrospinning technique. It is a highly efficient and binder-free catalyst for the direct reduction and carboxylation of CO2 with halides. Formate with 91% Faradaic efficiency and 2-phenylpropionic acid with 99% yield could be obtained, respectively. Moreover, this catalyst has excellent stability and reusability.

摘要

通过静电纺丝技术制备了一种新型的Pt-NP@NCNF@CC复合材料。它是一种用于二氧化碳与卤化物直接还原和羧化反应的高效无粘结剂催化剂。分别可获得法拉第效率为91%的甲酸盐和产率为99%的2-苯基丙酸。此外,该催化剂具有优异的稳定性和可重复使用性。

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