评论“五氮阴离子 -N 在 (N)(HO)(NH)Cl 中的合成与表征”。

Comment on "Synthesis and characterization of the pentazolate anion -N in (N)(HO)(NH)Cl".

机构信息

Anhui Key Laboratory of Functional Coordination Compounds and College of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, P. R. China.

出版信息

Science. 2018 Mar 16;359(6381). doi: 10.1126/science.aao3672.

DOI:10.1126/science.aao3672

PMID:29590051

Abstract

Zhang (Reports, 27 January 2017, p. 374) reported synthesis of a -N ion putatively stabilized in a solid-state salt by hydrogen bonding from surrounding counterions. We performed theoretical calculations suggesting that HN would be favored over the anion in the reported pentazolate salt via proton transfer.

摘要

张（报道，2017 年 1 月 27 日，第 374 页）报道了通过氢键与周围抗衡离子相互作用稳定在固态盐中的 -N 离子的合成。我们进行了理论计算，表明在报道的戊唑酸盐中，通过质子转移，HN 将优先于阴离子。