碳二亚胺作为硼烷还原 CO 的催化剂。
Carbodiimides as catalysts for the reduction of CO with boranes.
机构信息
Departamento de Química Inorgánica, Orgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, Universidad de Castilla-La Mancha, Campus Universitario, E-13071 Ciudad Real, Spain.
出版信息
Chem Commun (Camb). 2018 May 3;54(37):4700-4703. doi: 10.1039/c8cc02139b.
PMID:29676770
Abstract
Carbodiimides catalyse the reduction of CO2 with H-BBN or BH3·SMe2 to give either mixtures of CH2(OBBN)2 and CH3OBBN or (MeOBO)3 and B(OMe)3 under mild conditions (25-60 °C, 1 atm CO2). Stoichiometric reactions and theoretical calculations were performed to unveil the mechanism of these catalytic processes.
摘要
碳二亚胺催化 H-BBN 或 BH3·SMe2 将 CO2 还原为 CH2(OBBN)2 和 CH3OBBN 的混合物或 (MeOBO)3 和 B(OMe)3，反应条件温和（25-60°C，1 atm CO2）。进行了计量反应和理论计算以揭示这些催化过程的机制。
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