Kayama Masahiro, Tomioka Naotaka, Ohtani Eiji, Seto Yusuke, Nagaoka Hiroshi, Götze Jens, Miyake Akira, Ozawa Shin, Sekine Toshimori, Miyahara Masaaki, Tomeoka Kazushige, Matsumoto Megumi, Shoda Naoki, Hirao Naohisa, Kobayashi Takamichi
Department of Earth and Planetary Materials Science, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
Creative Interdisciplinary Research Division, Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai 980-8578, Japan.
Sci Adv. 2018 May 2;4(5):eaar4378. doi: 10.1126/sciadv.aar4378. eCollection 2018 May.
Moganite, a monoclinic SiO phase, has been discovered in a lunar meteorite. Silica micrograins occur as nanocrystalline aggregates of mostly moganite and occasionally coesite and stishovite in the KREEP (high potassium, rare-earth element, and phosphorus)-like gabbroic-basaltic breccia NWA 2727, although these grains are seemingly absent in other lunar meteorites. We interpret the origin of these grains as follows: alkaline water delivery to the Moon via carbonaceous chondrite collisions, fluid capture during impact-induced brecciation, moganite precipitation from the captured HO at pH 9.5 to 10.5 and 363 to 399 K on the sunlit surface, and meteorite launch from the Moon caused by an impact at 8 to 22 GPa and >673 K. On the subsurface, this captured HO may still remain as ice at estimated bulk content of >0.6 weight %. This indicates the possibility of the presence of abundant available water resources underneath local sites of the host bodies within the Procellarum KREEP and South Pole Aitken terranes.
莫来石是一种单斜晶系的SiO相,已在一块月球陨石中被发现。在类KREEP(高钾、稀土元素和磷)的辉长岩-玄武岩角砾岩NWA 2727中,二氧化硅微晶粒以主要为莫来石且偶尔为柯石英和斯石英的纳米晶聚集体形式出现,不过这些晶粒在其他月球陨石中似乎并不存在。我们对这些晶粒的成因解释如下:通过碳质球粒陨石碰撞向月球输送碱性水,撞击诱发角砾岩化过程中流体捕获,在光照面pH值为9.5至10.5且温度为363至399K的条件下从捕获的H₂O中沉淀出莫来石,以及由8至22吉帕和>673K的撞击导致陨石从月球发射。在地下,这种捕获的H₂O可能仍以冰的形式存在,估计总体含量>0.6重量%。这表明在风暴洋KREEP地体和南极艾特肯地体主体的局部区域下方可能存在丰富的可用水资源。