从菲并苯二炔大环到 S-杂环芳烃。
From Phenanthrylene Butadiynylene Macrocycles to S-Heterocycloarenes.
机构信息
Department of Chemistry , The Chinese University of Hong Kong , Shatin , New Territories, Hong Kong , China.
出版信息
Org Lett. 2018 Jul 20;20(14):4259-4262. doi: 10.1021/acs.orglett.8b01668. Epub 2018 Jun 28.
PMID:29953241
Abstract
The first member of S-heterocycloarenes was synthesized from an easily prepared phenanthrylene ethynylene macrocycle through diyne cyclocondensation and a Scholl reaction. The solution-processed thin film of this S-heterocycloarene behaved as a p-type semiconductor.
摘要
第一个 S-杂芳环化合物是通过二炔环缩合和施罗反应，从一个容易制备的菲并[9,10-b]乙炔大环合成的。这种 S-杂芳环的溶液处理薄膜表现为 p 型半导体。
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