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钙锆氧化物/钛酸锶界面处的极端可重构纳米电子学

Extreme Reconfigurable Nanoelectronics at the CaZrO /SrTiO Interface.

作者信息

Chen Lu, Li Jianan, Tang Yuhe, Pai Yun-Yi, Chen Yunzhong, Pryds Nini, Irvin Patrick, Levy Jeremy

机构信息

Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, PA, 15260, USA.

Pittsburgh Quantum Institute, Pittsburgh, PA, 15260, USA.

出版信息

Adv Mater. 2018 Jul 1:e1801794. doi: 10.1002/adma.201801794.

Abstract

Complex oxide heterostructures have fascinating emergent properties that originate from the properties of the bulk constituents as well as from dimensional confinement. The conductive behavior of the polar/nonpolar LaAlO /SrTiO interface can be reversibly switched using conductive atomic force microscopy (c-AFM) lithography, enabling a wide range of devices and physics to be explored. Here, extreme nanoscale control over the CaZrO /SrTiO (CZO/STO) interface, which is formed from two materials that are both nonpolar, is reported. Nanowires with measured widths as narrow as 1.2 nm are realized at the CZO/STO interface at room temperature by c-AFM lithography. These ultrathin nanostructures have spatial dimensions at room temperature that are comparable to single-walled carbon nanotubes, and hold great promise for alternative oxide-based nanoelectronics, as well as offer new opportunities to investigate the electronic structure of the complex oxide interfaces. The cryogenic properties of devices constructed from quasi-1D channels, tunnel barriers, and planar gates exhibit gate-tunable superconductivity, quantum oscillations, electron pairing outside of the superconducting regime, and quasi-ballistic transport. This newly demonstrated ability to control the metal-insulator transition at nonpolar oxide interface greatly expands the class of materials whose behavior can be patterned and reconfigured at extreme nanoscale dimensions.

摘要

复杂氧化物异质结构具有迷人的新兴特性,这些特性源于块体组分的性质以及尺寸限制。利用导电原子力显微镜(c-AFM)光刻技术,可以可逆地切换极性/非极性LaAlO₃/SrTiO₃界面的导电行为,从而能够探索各种器件和物理现象。在此,报道了对由两种均为非极性的材料形成的CaZrO₃/SrTiO₃(CZO/STO)界面的极端纳米尺度控制。通过c-AFM光刻技术在室温下在CZO/STO界面实现了宽度窄至1.2 nm的纳米线。这些超薄纳米结构在室温下的空间尺寸与单壁碳纳米管相当,在替代氧化物基纳米电子学方面具有巨大潜力,同时也为研究复杂氧化物界面的电子结构提供了新机会。由准一维通道、隧道势垒和平面栅极构成的器件的低温特性表现出门控可调超导性、量子振荡、超导区域之外的电子配对以及准弹道输运。这种新展示的在非极性氧化物界面控制金属-绝缘体转变的能力极大地扩展了其行为可以在极端纳米尺度上进行图案化和重新配置的材料类别。

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