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电子垃圾拆解区土壤重金属的空间变异及其分布特征

[Spatial Variation of Soil Heavy Metals in an E-waste Dismantling Area and Their Distribution Characteristics].

作者信息

Zhao Ke-Li, Fu Wei-Jun, Ye Zheng-Qian, Dai Wei

机构信息

Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, School of Environmental and Resources Science, Zhejiang A&F University, Lin'an 311300, China.

出版信息

Huan Jing Ke Xue. 2016 Aug 8;37(8):3151-3159. doi: 10.13277/j.hjkx.2016.08.042.

Abstract

A total of 90 soil samples were collected from the study area. The spatial variation of soil heavy metals and their spatial distribution characteristics were studied. The results indicated that the mean soil concentrations of five heavy metals including Cd, Cu, Zn, Pb and Ni were 0.38, 35.13, 121.38, 35.40 and 28.13 mg·kg, respectively. Compared with the background values in Zhejiang, the heavy metals were enriched in paddy soils of the study area. Part of study area was seriously contaminated by heavy metals. For the soil Cd, it had obvious contamination characteristics with a high value (>1). The Cd, and Pb concentrations in paddy soil had strong coefficients of variance (C.V.): 121.05% and 109.38%, respectively. Soil pH and organic matter (SOM) had significant correlations with most of the total heavy metals and their available fractions in soils. The total heavy metals and their available fractions also had strong correlations, such as total Cd and available Cd in soils. Geostatistics and the Local Moran's Ⅰ were used to identify the contaminated hotspots of these five metals. It was found out that the high soil Cd, Cu, Zn, Pb were located in Daxi and Zeguo towns, which could be attributed to E-waste dismantling and other anthropogenic activities. Soil Ni was mainly influenced by the parent material. The heavy metals in soils may pose a potential threat to local ecosystem and human health.

摘要

共从研究区域采集了90个土壤样本。研究了土壤重金属的空间变异及其空间分布特征。结果表明,镉(Cd)、铜(Cu)、锌(Zn)、铅(Pb)和镍(Ni)这五种重金属的土壤平均含量分别为0.38、35.13、121.38、35.40和28.13mg·kg。与浙江的背景值相比,研究区域的水稻土中重金属出现了富集。研究区域部分地区受到重金属的严重污染。对于土壤镉而言,其具有明显的污染特征,污染值较高(>1)。水稻土中镉和铅的浓度具有很强的变异系数(C.V.),分别为121.05%和109.38%。土壤pH值和有机质(SOM)与土壤中大多数重金属总量及其有效态部分具有显著相关性。重金属总量及其有效态部分之间也具有很强的相关性,例如土壤中的总镉和有效镉。利用地统计学和局部莫兰指数(Local Moran's Ⅰ)来识别这五种金属的污染热点。结果发现,土壤镉、铜、锌、铅含量高的区域位于大溪镇和泽国镇,这可能归因于电子垃圾拆解等人为活动。土壤镍主要受母质影响。土壤中的重金属可能会对当地生态系统和人类健康构成潜在威胁。

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