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展示细菌多糖 FucoPol 使高岭土悬浮液絮凝的能力。

Demonstration of the ability of the bacterial polysaccharide FucoPol to flocculate kaolin suspensions.

机构信息

UCIBIO-REQUIMTE, Chemistry Department, Faculty of Sciences and Technology, Universidade NOVA de Lisboa, Caparica, Portugal.

i3N/CENIMAT, Department of Materials Science, Faculty of Sciences and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Caparica, Portugal.

出版信息

Environ Technol. 2020 Jan;41(3):287-295. doi: 10.1080/09593330.2018.1497710. Epub 2018 Jul 13.

Abstract

In this study, the flocculation properties of FucoPol, a bacterial extracellular polysaccharide, were investigated. FucoPol is a high molecular weight polymer and negatively charged due to the presence of glucuronic acid and the acyl groups succinyl and pyruvyl. High flocculation rate values (>70%) were achieved with a low bioflocculant dosage of 1 mg/L, for pH values in the range 3-5 and temperature within 15-20°C. The bioflocculant was also shown to be stable after freezing/thawing and heating up to 100°C. Given the polymer's anionic character, the size of flocs formed and their surface profile, bridging seems to be the main flocculation mechanism of FucoPol. This study demonstrated that FucoPol is a promising natural, biodegradable and biocompatible alternative to the currently used synthetic or inorganic hazardous products, with potential to be used as a novel flocculation agent in several applications, such as water treatment, food or mining. Further studies will involve evaluating the reduction of cation dosage on flocculation efficiency, as well as testing the applicability of FucoPol to flocculate different types of suspended solids, such as, for example, activated carbons, soil solids or yeast cells.

摘要

在这项研究中,研究了一种细菌胞外多糖 FucoPol 的絮凝特性。FucoPol 是一种高分子量聚合物,由于存在葡萄糖醛酸和琥珀酰基及丙酮酸基,因此带负电荷。在 pH 值为 3-5 且温度在 15-20°C 范围内时,只需 1mg/L 的低生物絮凝剂剂量即可实现>70%的高絮凝率。该生物絮凝剂在冷冻/解冻和加热至 100°C 后也表现出稳定性。鉴于聚合物的阴离子特性,形成的絮体的大小及其表面轮廓,桥接似乎是 FucoPol 的主要絮凝机制。这项研究表明,FucoPol 是一种有前途的天然、可生物降解和生物相容的替代物,可以替代目前使用的合成或无机危险产品,具有在水处理、食品或采矿等多种应用中用作新型絮凝剂的潜力。进一步的研究将涉及评估阳离子剂量对絮凝效率的降低,以及测试 FucoPol 对不同类型悬浮固体(例如活性炭、土壤固体或酵母细胞)的絮凝适用性。

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