Ma Chengkun, Tian Yuan, Gong Yan, Zhang Jifeng, Qi Hui, Wang Chao
Smart Structures and Advanced Composite Materials Lab, College of Aerospace and Civil Engineering, Harbin Engineering University, Harbin 150001, China.
School of Materials Science and Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China.
Materials (Basel). 2018 Jul 12;11(7):1198. doi: 10.3390/ma11071198.
High-temperature phosphate adhesives are widely used in the aerospace and nuclear power industries. However, complex residual stresses can result when the curing temperature parameters are unreasonable due to the brittleness of the adhesive. To reveal the curing temperature mechanism affecting the bonding strength of the phosphate adhesives, several curing temperature curves (CT-1~6) were designed for the single lap joint (SLJ) using phosphate adhesive. The residual stress helped to reveal the relationship between the curing temperature parameters and the bonding performance. In this process, the residual stress of the silicon carbide joint was measured using micro-Raman spectroscopy, and the tensile strength of the joint was tested. A cohesive zone model (CZM) was established with Abaqus to verify the results, and the numerical results from the model agreed well with the experimental values. The residual stress and adhesive strength were obviously affected by curing temperature. The reasonable curing temperature curves have the benefits of reducing the residual stress and improving the bonding strength.
高温磷酸盐胶粘剂广泛应用于航空航天和核电工业。然而,由于胶粘剂的脆性,当固化温度参数不合理时会产生复杂的残余应力。为了揭示影响磷酸盐胶粘剂粘结强度的固化温度机制,针对使用磷酸盐胶粘剂的单搭接接头(SLJ)设计了几条固化温度曲线(CT-1~6)。残余应力有助于揭示固化温度参数与粘结性能之间的关系。在此过程中,使用显微拉曼光谱法测量了碳化硅接头的残余应力,并对接头的拉伸强度进行了测试。利用Abaqus建立了内聚区模型(CZM)以验证结果,模型的数值结果与实验值吻合良好。残余应力和胶粘剂强度明显受固化温度的影响。合理的固化温度曲线具有降低残余应力和提高粘结强度的优点。