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[基于固相微萃取-气相色谱-质谱联用技术对降香檀及黄檀属植物的鉴别]

[Identification of dalbergia odorifera and dalbergia spp by solid phase microextraction-gas chromatography-mass spectrometry].

作者信息

Hou Sirun, Huang Xiaolan, Ma Yanfang, Huang Fang, Lin Xiaoshan, Ma Yefen, Zhu Zhixin, Luo Huitai, Wu Huiqin

机构信息

Guangdong Institute of Analysis, Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals, Guangzhou 510070, China.

出版信息

Se Pu. 2018 May 8;36(5):493-498. doi: 10.3724/SP.J.1123.2017.11058.

Abstract

In addition to species identification, the volatile components of dalbergia odorifera and dalbergia spp, were investigated by solid phase microextraction-gas chromatography-mass spectrometry (SPME-GC-MS). Small amounts of powder samples were acquired by drilling from dalbergia, then the volatile components of the powder samples were concentrated by SPME, and separated by AB-FFAP polar capillary GC column. Of all the volatile components, twenty types were identified, and two pairs of them, 2-(1,1-dimethylethyl)-5-heptyl-5-methyl-1,3-dioxolan-4-one and 2,6,10-trimethyl-7,10-epoxy-2,11-dodecadien-6-ol, 2-methylbutylidene-cyclopentane and 2-(5-methyl-furan-2-yl)-propionaldehyde, could be considered specific volatile components for the identification of dalbergia odorifera and dalbergia spp, and the relative contents of these two pairs were compared for the species identification analysis. The method has the advantages of less sample requirement, simple operation, and no construction damage. The method is suitable for the research of volatile components and species identification analysis of dalbergia odorifera and dalbergia spp, and has broad prospective application in the analysis of furniture, art collections and raw wood of dalbergia.

摘要

除物种鉴定外,还采用固相微萃取-气相色谱-质谱联用(SPME-GC-MS)技术对降香檀及黄檀属植物的挥发性成分进行了研究。通过在降香檀上钻孔获取少量粉末样品,然后用固相微萃取法浓缩粉末样品中的挥发性成分,并用AB-FFAP极性毛细管气相色谱柱进行分离。在所有挥发性成分中,共鉴定出20种,其中2-(1,1-二甲基乙基)-5-庚基-5-甲基-1,3-二氧杂环戊烷-4-酮与2,6,10-三甲基-7,10-环氧-2,11-十二碳二烯-6-醇、2-甲基亚丁基环戊烷与2-(5-甲基-呋喃-2-基)丙醛这两对成分可被视为降香檀及黄檀属植物的特异性挥发性成分,并比较了这两对成分的相对含量以进行物种鉴定分析。该方法具有样品用量少、操作简便、不破坏结构等优点。该方法适用于降香檀及黄檀属植物挥发性成分的研究和物种鉴定分析,在降香檀家具、艺术品收藏及原木分析方面具有广阔的应用前景。

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