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催化同功能反应——拓展穿梭和复分解反应的应用范围。

Catalytic Isofunctional Reactions-Expanding the Repertoire of Shuttle and Metathesis Reactions.

机构信息

Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der Ruhr, Germany.

Laboratorium für Organische Chemie, ETH Zürich, 8093, Zürich, Switzerland.

出版信息

Angew Chem Int Ed Engl. 2019 Jul 22;58(30):10074-10103. doi: 10.1002/anie.201803797. Epub 2019 Apr 30.

Abstract

Transfer hydrogenation, alkene metathesis, and alkyne metathesis possess great value to the synthetic chemistry community. One of the key features of these processes is their reversibility, which can be attributed to the presence of the same number and type of functional groups in both the reactants and products, making these reactions isofunctional. These classic reactions have recently inspired the development of novel shuttle and metathesis reactions that offer great promise for synthetic chemistry. This Review describes and systematically categorizes both recent and older examples of shuttle and metathesis reactions other than transfer hydrogenation and alkene/alkyne metathesis.

摘要

转移氢化、烯烃易位和炔烃易位对合成化学界具有重要价值。这些过程的一个关键特征是它们的可逆性,这归因于反应物和产物中具有相同数量和类型的官能团,使得这些反应具有同功能。这些经典反应最近激发了新型穿梭和易位反应的发展,为合成化学带来了巨大的前景。本文综述了除转移氢化和烯烃/炔烃易位以外的新型穿梭和易位反应的近期和较早期的例子,并对其进行了描述和系统分类。

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