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[重庆城郊雪玉洞流域大气无机氮湿沉降特征及来源]

[Characteristics and Sources of Atmospheric Inorganic Nitrogen Wet Deposition in Xueyu Cave Watershed, Outer Suburbs of Chongqing City].

作者信息

Duan Shi-Hui, Jiang Yong-Jun, Zhang Yuan-Zhu, Hu Liu-Chan, Zeng Ze, Lü Xian-Fu

机构信息

Chongqing Key Laboratory of Karst Environment, School of Geographical Sciences, Southwest University, Chongqing 400715, China.

出版信息

Huan Jing Ke Xue. 2018 Oct 8;39(10):4479-4489. doi: 10.13227/j.hjkx.201711053.

Abstract

Xueyu Cave watershed is located in Fengdu County in the outskirts of Chongqing, where rainfall events were monitored continuously from July 2015 to December 2017. We explored the variation of mass concentration of atmospheric dissolved inorganic nitrogen (NH-N and NO-N), and quantitatively calculated its wet deposition fluxes, then the sources of NH-N and NO-N were tracked using the Xueyu cave air mass backward trajectory model. The results showed that:①During the monitoring period, the average annual dissolved inorganic nitrogen (DIN) deposition in the watershed was 14.25 kg·(hm·a), of which NH-N and NO-N were 7.72 kg·(hm·a) and 6.53 kg·(hm·a), accounting for 54% and 46% of DIN wet precipitation, respectively, and indicating that NH-N is the dominant species, followed by NO-N; ②DIN wet deposition flux and concentration showed marked seasonal changes. The DIN wet deposition flux in spring and summer was 50% higher than that in autumn and winter, while the DIN concentration of wet deposition in autumn and winter was 30% higher than those in spring and summer. ③NH-N/NO-N was between 0.29 and 2.27, and NH-N/NO-N > 1 during the rainy season (April to October) and NH-N/NO-N < 1 during the dry season (November to March), indicating that the main sources of DIN wet deposition results from agricultural activities in the rainy season, and urban contributions in the dry season. ④In the study area, the southeastern winds are dominant in the rainy season but southwestern winds are dominant in the dry season. These determine the sources of DIN wet deposition (agricultural or urban).

摘要

雪玉洞流域位于重庆郊区的丰都县,于2015年7月至2017年12月对降雨事件进行了连续监测。我们探究了大气溶解无机氮(NH-N和NO-N)质量浓度的变化,定量计算了其湿沉降通量,然后利用雪玉洞气团后向轨迹模型追踪了NH-N和NO-N的来源。结果表明:①监测期内,流域年均溶解无机氮(DIN)沉降量为14.25 kg·(hm·a),其中NH-N和NO-N分别为7.72 kg·(hm·a)和6.53 kg·(hm·a),分别占DIN湿沉降的54%和46%,表明NH-N是主要成分,其次是NO-N;②DIN湿沉降通量和浓度呈现明显的季节变化。春季和夏季的DIN湿沉降通量比秋季和冬季高50%,而秋季和冬季的湿沉降DIN浓度比春季和夏季高30%。③NH-N/NO-N在0.29至2.27之间,雨季(4月至10月)NH-N/NO-N>1,旱季(11月至3月)NH-N/NO-N<1,表明雨季DIN湿沉降的主要来源是农业活动,旱季则是城市贡献。④在研究区域,雨季以东南风为主,旱季以西南风为主。这些决定了DIN湿沉降的来源(农业或城市)。

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