a School of Energy Science and Engineering , Central South University , Changsha , China.
b Research Institute of Petroleum Exploration & Development , Beijing , China.
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2019;54(1):48-55. doi: 10.1080/10934529.2018.1511363. Epub 2018 Sep 19.
The initial emittable concentration, C, the material phase diffusion coefficient, D, and the air/material partition coefficient, K, are the key parameters used to predict the formaldehyde emissions from indoor building materials. This work presents formaldehyde emission experiments of plywood panels in a climatic chamber under various environmental conditions, which provides information on how relative humidity, temperature, and loading degree affect the formaldehyde emission. The experimental results showed that formaldehyde concentration in the climatic chamber increased rapidly during the initial 3 h, and then reached equilibrium after 7 h. The equilibrium concentration of formaldehyde in the closed chamber was increased by 1.1-1.3 times with the relative humidity increased by 20%, and 1.3-2.5 times with the temperature increased by 5 °C, respectively. In agreement with the experimental treatment, a new method of estimating parameters was carried out in a theoretical model from formaldehyde emission, opening the way to a factorial analysis of the relevant parameters for relative humidity and temperature. The theoretical model with estimated parameters was further validated by experiments with different environmental conditions, which should help to quickly determine the parameters needed to predict formaldehyde emissions.
初始散发浓度 C、物质相扩散系数 D 和空气/物质分配系数 K 是预测室内建筑材料甲醛散发的关键参数。本工作在气候室内进行了胶合板的甲醛散发实验,研究了不同环境条件下相对湿度、温度和负荷程度对甲醛散发的影响。实验结果表明,在初始 3 h 内,气候室内的甲醛浓度迅速增加,7 h 后达到平衡。相对湿度增加 20%,平衡时封闭室内的甲醛浓度增加 1.1-1.3 倍;温度升高 5°C,甲醛浓度增加 1.3-2.5 倍。根据实验处理,从甲醛散发理论模型中采用一种新的参数估计方法,对相对湿度和温度的相关参数进行了析因分析。用不同环境条件进行实验对具有估计参数的理论模型进行了验证,这有助于快速确定预测甲醛散发所需的参数。