Department of Physics, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.
Soft Matter. 2018 Nov 14;14(44):9005-9011. doi: 10.1039/c8sm01829d.
This study introduces cylindrical nematic liquid crystal (LC) shells. Shells as confinement can provide soft matter with intriguing topology and geometry. Indeed, in spherical shells of LCs, rich defect structures have been reported. Avoiding the inherent Plateau-Rayleigh instability of cylindrical liquid-liquid interfaces, we realize the cylindrical nematic LC shell by two different methods: the phase separation in the nematic-isotropic coexistence phase and a cylindrical cavity with a glass rod suspended in the middle. Specifically, the director configurations of lyotropic chromonic LCs (LCLCs) in the cylindrical shell and their energetics are investigated theoretically and experimentally. Unusual elastic properties of LCLCs, i.e., a large saddle-splay modulus, and a shell geometry with both concave and convex curvatures, result in a double-twist director configuration.
本研究介绍了圆柱向列相液晶(LC)壳。壳作为约束可以为软物质提供有趣的拓扑和几何形状。事实上,在 LC 的球形壳中,已经报道了丰富的缺陷结构。通过两种不同的方法避免圆柱液-液界面固有的 Plateau-Rayleigh 不稳定性,我们实现了圆柱向列 LC 壳:向列-各向同性共存相的相分离和中间悬挂玻璃棒的圆柱腔。具体而言,从理论和实验上研究了溶致变色向列相液晶(LCLC)在圆柱壳中的取向配置及其能量。LCLC 的异常弹性特性,即大的扭曲柔量和具有凹面和凸面曲率的壳几何形状,导致双螺旋取向配置。