铜基金属卡宾对 C F (O)SO 自由基的快速捕获：一种新型全氟烷基亚磺酸盐酯的合成方法。
Rapid Interception of C F (O)SO Radical with Copper-Based Carbene: A Novel Access to Perfluoroalkanesulfinate Ester.
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road, Suzhou, Jiangsu, 215123, P. R. China.
出版信息
Chemistry. 2019 Feb 11;25(9):2195-2198. doi: 10.1002/chem.201805639. Epub 2019 Jan 16.
In this communication, an unprecedented interception of C F (O)SO radical with a copper-based carbene has been established. Distinguished by wide substrate scopes and mild reaction conditions, this novel radical-carbene coupling reaction (RCC reaction) provides a fundamentally different and mechanistically interesting strategy for the synthesis of perfluoroalkanesulfinate esters.
在本通讯中，建立了铜基卡宾与 C F (O)SO 自由基的空前拦截。这种新型自由基-卡宾偶联反应（RCC 反应）具有广泛的底物范围和温和的反应条件，为全氟烷基亚磺酸盐酯的合成提供了一种截然不同且具有机理意义的策略。
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