Sun Mian, Chen Youzhi, Zhu Jiaoqun, Sun Tao, Shui Zhonghe, Ling Gang, Zhong Haoxuan
State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China.
School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China.
Materials (Basel). 2018 Dec 22;12(1):37. doi: 10.3390/ma12010037.
:Polyvinyl alcohol (PVA) fiber was proposed to enhance the mechanical performance of engineered cementitious composite in this research. A mixture of engineered cementitious composite with better expected performance was made by adding 2% PVA fiber. Mechanics tests, including pressure resistance, fracture resistance, and ultimate tensile strength, were conducted. They reveal that the engineered cementitious composites not only exhibit good pressure resistance, but they also exhibit excellent fracture resistance and strain capability against tensile stress through mechanics tests, including pressure resistance, fracture resistance, and ultimate tensile resistance. To further improve the engineered composites' ductility, attempts to modify the performance of the PVA fiber surface have been made by using a vinyl acetate (VAE) emulsion, a butadiene⁻styrene emulsion, and boric anhydride. Results indicated that the VAE emulsion achieved the best performance improvement. Its use in fiber pre-processing enables the formation of a layer of film with weak acidity, which restrains the hydration of adjacent gel materials, and reduces the strength of transitional areas of the fiber/composite interface, which restricts fiber slippage and pulls out as a result of its growth in age, and reduces hydration levels. Research illustrates that the performance-improvement processing that is studied not only improves the strain of the engineered cementitious composites, but can also reduce the attenuation of the strain against tensile stress.
本研究提出使用聚乙烯醇(PVA)纤维来增强工程水泥基复合材料的力学性能。通过添加2%的PVA纤维制成了具有更好预期性能的工程水泥基复合材料混合物。进行了包括抗压强度、抗折强度和极限抗拉强度在内的力学试验。试验结果表明,工程水泥基复合材料不仅具有良好的抗压性能,而且通过抗压强度、抗折强度和极限抗拉强度等力学试验,还表现出优异的抗折性能和抗拉应力应变能力。为了进一步提高工程复合材料的延展性,已尝试使用醋酸乙烯酯(VAE)乳液、丁苯乳液和硼酸酐来改善PVA纤维表面的性能。结果表明,VAE乳液的性能改善效果最佳。在纤维预处理中使用VAE乳液能够形成一层弱酸性薄膜,抑制相邻凝胶材料的水化作用,降低纤维/复合材料界面过渡区域的强度,从而限制纤维随着时间增长而发生的滑移和拔出,并降低水化程度。研究表明,所研究的性能改进工艺不仅提高了工程水泥基复合材料的应变能力,还能减少抗拉应力应变的衰减。