Wang Zheng, Wang Jin-Guo, Chen Ze-Yu, Zha Min, Wang Cheng, Liu Shi, Yan Rui-Fang
Key Laboratory of Automobile Materials of Ministry of Education & School of Materials Science and Engineering, Nanling Campus, Jilin University, No. 5988 Renmin Street, Changchun 130025, China.
Materials (Basel). 2018 Dec 26;12(1):76. doi: 10.3390/ma12010076.
Forming magnesium alloys with rare earth elements (La, Gd, Nd, Y, Ce) is a routine method for modifying their microstructure and properties. In the present work, the effect of Ce addition on the microstructure evolution and the mechanical properties of as-extruded Mg-8Al-0.5Zn (AZ80) alloy was investigated. All of the extruded AZ80-Ce ( = 0, 0.2, 0.8 and 1.4 wt %) alloys exhibited equiaxed grains formed by fully dynamic recrystallization, and the grain size of the extruded AZ80 alloy was remarkably reduced by ~56.7% with the addition of 1.4 wt % Ce. Furthermore, the bulk-shaped Al₄Ce phase formed when Ce was first added, with the Ce content rising to 0.8 wt % or higher, and Al₄Ce particles in both the nano- and micron sizees were well distributed in the primary -Mg matrix. The area fraction of the Al₄Ce particles expanded with increasing Ce content, providing more nuclei for dynamic recrystallization, which could contribute to the grain refinement. The results of the tensile tests in this study showed that Ce addition effectively improved the room temperature formability of the as-extruded AZ80 alloy, without sacrificing strength. The significantly improved mechanical properties were ascribed to excellent grain refinement, weakened texture strength, an increased Schmid factor, and a reduced area fraction of low-angle grain boundaries, all resulting from Ce addition to the as-extruded AZ80 alloy. The contribution of the nano-Al₄Ce precipitates on improving the mechanical properties was also discussed in this paper.
添加稀土元素(镧、钆、钕、钇、铈)形成镁合金是改善其微观结构和性能的常规方法。在本研究中,研究了添加铈对挤压态Mg-8Al-0.5Zn(AZ80)合金微观结构演变和力学性能的影响。所有挤压态AZ80-Ce(铈含量分别为0、0.2、0.8和1.4 wt%)合金均呈现出由完全动态再结晶形成的等轴晶粒,添加1.4 wt%铈后,挤压态AZ80合金的晶粒尺寸显著减小了约56.7%。此外,首次添加铈时会形成块状Al₄Ce相,当铈含量升至0.8 wt%或更高时,纳米和微米尺寸的Al₄Ce颗粒均良好地分布在初生α-Mg基体中。Al₄Ce颗粒的面积分数随铈含量的增加而增大,为动态再结晶提供了更多形核点,有助于细化晶粒。本研究的拉伸试验结果表明,添加铈有效地提高了挤压态AZ80合金的室温成形性,且不牺牲强度。力学性能的显著改善归因于优异的晶粒细化、弱化的织构强度、增加的施密德因子以及低角度晶界面积分数的减小,这些均源于向挤压态AZ80合金中添加铈。本文还讨论了纳米Al₄Ce析出相对改善力学性能的贡献。