[九龙江流域稻田土壤重金属形态及污染状况评估]

[Assessment of the Speciation and Pollution of Heavy Metals in Paddy Soils from the Jiulong River Basin].

作者信息

Lin Cheng-Qi, Huang Hua-Bin, Hu Gong-Ren, Yu Rui-Lian, Hao Chun-Li, Lin Ying

机构信息

Department of Science and Technology for Inspection, Xiamen Huaxia University, Xiamen 361021, China.

Department of Environmental Science and Engineering, Huaqiao University, Xiamen 361021, China.

出版信息

Huan Jing Ke Xue. 2019 Jan 8;40(1):453-460. doi: 10.13227/j.hjkx.201805152.

Abstract

Speciation characteristics of twelve heavy metals in 71 paddy soils from the Jiulong River Basin were analyzed using inductively coupled plasma mass spectrometry (ICP-MS) and the modified BCR protocol. The risk assessment coding method (RAC), ratio of secondary phase and primary phase (RSP), and geoaccumulation index (I) were applied to evaluate the pollution degree of heavy metals in the area. The results show that most of these elements are abundant in the paddy soils and the speciation characteristics of different heavy metals vary. The elements Cd and Mn mainly exist as acid soluble fractions in the soils, with a mean proportion of 46.2% and 35.2%, respectively; Fe and Pb mainly exist as reducible fractions in the soils, with a mean proportion of 64.5% and 41.5%, respectively; and V, Cr, Ni, As, Co, Sr, Zn, and Cu mainly exist as residual fractions in the soils, with a mean proportion of 79.6%, 78.4%, 73.1%, 67.7%, 51.9%, 49.7%, 45.3%, and 38.4%, respectively. The three pollution assessment methods focus on the acid-soluble phase, secondary phase, and total amount of heavy metals, respectively. All have their own application value and disadvantages of incompletion. The comprehensive analysis of these three pollution assessment methods helps to more accurately and comprehensively assess the pollution characteristics of the heavy metals. The results show that the paddy soils are moderately to severely polluted with Cd; the Mn and Sr pollution is mild to severe; the Zn, Pb, Cu, and Co pollution is mild to moderate; the As and Ni pollution is absent or moderate; and V, Fe, and Cr pollution is non-existent or mild.

摘要

采用电感耦合等离子体质谱法(ICP-MS)和改进的BCR法,分析了九龙江流域71个水稻土中12种重金属的形态特征。应用风险评估编码法(RAC)、次生相与原生相比值(RSP)和地累积指数(I)评价该地区重金属污染程度。结果表明,这些元素在水稻土中大多含量丰富,不同重金属的形态特征各异。土壤中Cd和Mn主要以酸溶态存在,平均占比分别为46.2%和35.2%;Fe和Pb主要以可还原态存在,平均占比分别为64.5%和41.5%;V、Cr、Ni、As、Co、Sr、Zn和Cu主要以残渣态存在,平均占比分别为79.6%、78.4%、73.1%、67.7%、51.9%、49.7%、45.3%和38.4%。三种污染评价方法分别侧重于重金属的酸溶态、次生相和总量,各有其应用价值和不完整性的缺点。综合分析这三种污染评价方法有助于更准确、全面地评估重金属的污染特征。结果表明,水稻土Cd污染为中度至重度;Mn和Sr污染为轻度至重度;Zn、Pb、Cu和Co污染为轻度至中度;As和Ni污染不存在或为中度;V、Fe和Cr污染不存在或为轻度。

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