Shanghai Institute of Pollution Control and Ecological Security, College of Environmental Science and Engineering, Tongji University, Siping Road, Shanghai 200092, PR China.
Shanghai Institute of Pollution Control and Ecological Security, College of Environmental Science and Engineering, Tongji University, Siping Road, Shanghai 200092, PR China; UN Environment-Tongji Institute of Environment for Sustainable Development, Siping Road, Shanghai 200092, PR China.
Sci Total Environ. 2019 Mar 25;658:1006-1012. doi: 10.1016/j.scitotenv.2018.12.127. Epub 2018 Dec 11.
Iron is currently one of the main contaminants of drinking water. The inner walls of drinking pipes can cause iron to release in water chemistry, which alters the water quality, including its chloride, sulfate, bicarbonate, pH, and humic acid (HA) levels. Hence, the goal of this research was to improve our understanding of the multi-water quality factors affecting iron release in polyethylene pipes. An array of bench-scale experiments were conducted exposing model water with different concentrations of chloride, sulfate, bicarbonate, HA, and different pH levels to prepared polyethylene pipes following the response surface methodology. The single role of HA during iron release is also evaluated by changing its concentration. A comprehensive study revealed that regression models could be used to describe the relationship between the five water quality parameters and iron release. The coefficients of determination were 0.890 and 0.870 for the fitting equations of total and soluble iron concentrations in water, respectively. In the presence of HA, the concentration of iron in water increased more rapidly than that for the other four factors (chloride, sulfate, bicarbonate, and pH). In addition, the Visual MINTEQ results suggest that a lower HA concentration tended to increase the degree of saturation of iron solids. In turn, this limits iron release and considerably increases the iron concentration in water.
铁是目前饮用水的主要污染物之一。饮用水管道的内壁会导致铁在水化学中释放,从而改变水质,包括氯化物、硫酸盐、碳酸氢盐、pH 值和腐殖酸 (HA) 水平。因此,本研究的目的是提高我们对影响聚乙烯管中铁释放的多种水质因素的理解。通过响应面法,在一系列台式实验中,将不同浓度的氯化物、硫酸盐、碳酸氢盐、HA 和不同 pH 值的模型水暴露于制备好的聚乙烯管中。还通过改变 HA 的浓度来评估其在铁释放过程中的单一作用。全面的研究表明,可以使用回归模型来描述这五个水质参数与铁释放之间的关系。总铁和水溶铁浓度拟合方程的决定系数分别为 0.890 和 0.870。在 HA 存在的情况下,水中铁的浓度增加速度比其他四个因素(氯化物、硫酸盐、碳酸氢盐和 pH 值)更快。此外,Visual MINTEQ 结果表明,较低的 HA 浓度往往会增加铁固体的饱和度。反过来,这限制了铁的释放,并大大增加了水中的铁浓度。