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预辐照对液体中激光烧蚀时气泡形成和烧蚀的孵化效应。

Incubation Effect of Pre-Irradiation on Bubble Formation and Ablation in Laser Ablation in Liquids.

作者信息

Reich Stefan, Letzel Alexander, Gökce Bilal, Menzel Andreas, Barcikowski Stephan, Plech Anton

机构信息

Karlsruhe Institute of Technology (KIT), Institute for Photon Science and Synchrotron Radiation (IPS), Herrmann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.

University of Duisburg-Essen, Technical Chemistry I and Center for Nanointegration, Duisburg-Essen (CENIDE), Universitätsstrasse 7, 45141, Essen, Germany.

出版信息

Chemphyschem. 2019 Apr 16;20(8):1036-1043. doi: 10.1002/cphc.201900075. Epub 2019 Apr 5.

Abstract

Pulsed laser ablation in liquids (PLAL) is a multi-scale process, which is widely studied either in batch ablation with prolonged target irradiation as well as mechanistic investigations, in a defined (single-shot) process. However, fundamental studies on defined pulse series are rare. We have investigated the effect of a developing rough morphology of the target surface on the PLAL process with nanosecond pulses and, partially, picosecond pulses. At low fluence the cavitation bubble growth as well as the ablation yield depend on the irradiation history of the target. The bubble size increases with repeated irradiation on one spot for the first 2-30 pulses as well as with the applied dose. This is discussed within the framework of incubation effects. Incubation is found to be important, resulting in a bubble volume increase by a factor of six or more between pristine and corrugated targets. The target surface, changing from smooth to corrugated, induces a more efficient localization of laser energy at the solid-liquid interface. This is accompanied by a suppressed reflectivity and more efficient coupling of energy into the laser-induced plasma. Thus, the cavitation bubble size increases as well as ablation being enhanced. At high fluence, such incubation is masked by the rapid development of surface damage within the first shots, which eventually would lead to a reduction of bubble sizes.

摘要

液体中的脉冲激光烧蚀(PLAL)是一个多尺度过程,该过程在长时间照射靶材的批量烧蚀以及在特定(单次)过程中的机理研究中均得到了广泛研究。然而,关于特定脉冲序列的基础研究却很少。我们研究了靶材表面逐渐形成的粗糙形态对纳秒脉冲以及部分皮秒脉冲的PLAL过程的影响。在低能量密度下,空化气泡的生长以及烧蚀产率取决于靶材的辐照历史。在前2 - 30个脉冲中,在同一点重复照射时气泡尺寸会增大,且随着施加剂量的增加而增大。这在孵化效应的框架内进行了讨论。发现孵化效应很重要,在原始靶材和波纹靶材之间,气泡体积会增大六倍或更多。靶材表面从光滑变为波纹状,会使激光能量在固液界面处的定位更加高效。这伴随着反射率的降低以及能量更有效地耦合到激光诱导等离子体中。因此,空化气泡尺寸增大,烧蚀也得到增强。在高能量密度下,这种孵化效应会被首次照射时表面损伤的快速发展所掩盖,最终这会导致气泡尺寸减小。

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