Deep-Blue Thermally Activated Delayed Fluorescence Emitters Containing Diphenyl Sulfone Group for Organic Light Emitting Diodes.

Novel blue thermally activated delayed fluorescence (TADF) emitters, and , were designed and synthesized. Diphenyl sulfone (DPS) group functioned as a common acceptor, and it combined with each of two different spiro-acridine groups, D1 and D2. The calculated energy differences (Δ) of the singlet and triplet excited states of (0.062 eV) and (0.128 eV) had sufficiently small Δ values, which is favorable in the thermally activated reverse intersystem crossing (RISC) process from the T state to the S state. A device doped 10 wt% of D2-DPS with ADN host material, obtained 5.05% of external quantum efficiency with deep-blue emission having CIE coordinates of (0.152, 0.065). The results showed that these molecules are promising host-free TADF deep-blue emitters by inhibiting concentration quenching.