Luo Xiaomin, Hu Wenjie, Cao Min, Ren Huijun, Feng Jianyan, Wei Mengyuan
College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Polymers (Basel). 2018 Mar 30;10(4):378. doi: 10.3390/polym10040378.
A large amount of research has been devoted to developing novel superhydrophobic coatings. However, it is still a great challenge to pursuean environmentally friendly method that leads to superhydrophobic coatings. Herein, we demonstrate for the first time, an environmentally friendly method for the preparation of conductive superhydrophobic coatings with sandwich-like structures by using aminoethylaminopropyl polydimethylsiloxane modified waterborne polyurethane (SiWPU) and -octadecylamine functionalized multi-wall carbon nanotubes. These environmentally friendly coatings with the sheet resistance of 1.1 ± 0.1 kΩ/sq exhibit a high apparent contact angle of 158.1° ± 2° and a low sliding angle below 1°. The influence of the surface texture before and after heat treatment on the wetting properties is discussed. In addition, the coatings can be electrically heated by 3113 °C with a voltage of 1272 V, and thus, can be used for deicing. Furthermore, the resulting coatings demonstrate good performance of wear resistance and ultraviolet resistance, which will have broad application potential in harsh environments.
大量研究致力于开发新型超疏水涂层。然而,寻求一种能制备超疏水涂层的环保方法仍然是一个巨大的挑战。在此,我们首次展示了一种环保方法,通过使用氨基乙基氨丙基聚二甲基硅氧烷改性水性聚氨酯(SiWPU)和十八烷基胺功能化多壁碳纳米管来制备具有三明治结构的导电超疏水涂层。这些表面电阻为1.1±0.1 kΩ/sq的环保涂层表现出158.1°±2°的高表观接触角和低于1°的低滑动角。讨论了热处理前后表面纹理对润湿性的影响。此外,该涂层在1272 V电压下可实现3113 °C的电加热,因此可用于除冰。此外,所得涂层表现出良好的耐磨性和抗紫外线性,在恶劣环境中将具有广阔的应用潜力。