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金属基近红外和红外辐射 OLED 的最新进展。

Recent Advances on Metal-Based Near-Infrared and Infrared Emitting OLEDs.

机构信息

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, F-13397 Marseille, France.

Aix Marseille Univ, CNRS, ICR, UMR 7273, F-13397 Marseille, France.

出版信息

Molecules. 2019 Apr 10;24(7):1412. doi: 10.3390/molecules24071412.

DOI:10.3390/molecules24071412
PMID:30974838
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6480698/
Abstract

During the past decades, the development of emissive materials for organic light-emitting diodes (OLEDs) in infrared region has focused the interest of numerous research groups as these devices can find interest in applications ranging from optical communication to defense. To date, metal complexes have been most widely studied to elaborate near-infrared (NIR) emitters due to their low energy emissive triplet states and their facile access. In this review, an overview of the different metal complexes used in OLEDs and enabling to get an infrared emission is provided.

摘要

在过去的几十年中,有机发光二极管(OLED)中红外发光材料的发展引起了众多研究小组的关注,因为这些器件在从光通信到国防的各种应用中都具有潜在的应用价值。迄今为止,由于其低能量发射三重态和易于获得,金属配合物是研究近红外(NIR)发射器最广泛的材料。在这篇综述中,提供了用于 OLED 并能够实现红外发射的不同金属配合物的概述。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/02aa23d096a1/molecules-24-01412-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/3241876d7529/molecules-24-01412-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/b9dd8ba9a0a9/molecules-24-01412-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/29a8d1a13f45/molecules-24-01412-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/91eebf10209f/molecules-24-01412-g008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/02aa23d096a1/molecules-24-01412-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/3241876d7529/molecules-24-01412-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/b7bb96c86e76/molecules-24-01412-g002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/068ce6309262/molecules-24-01412-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/4bea22957fd3/molecules-24-01412-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/b9dd8ba9a0a9/molecules-24-01412-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/29a8d1a13f45/molecules-24-01412-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/91eebf10209f/molecules-24-01412-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/d8368e9c552c/molecules-24-01412-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/bb6bece0302f/molecules-24-01412-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/a1c966ea0684/molecules-24-01412-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cf3/6480698/02aa23d096a1/molecules-24-01412-g013.jpg

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本文引用的文献

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Chemistry. 2019 Apr 11;25(21):5489-5497. doi: 10.1002/chem.201805902. Epub 2019 Mar 19.
2
A near infrared light emitting electrochemical cell with a 2.3 V turn-on voltage.一种开启电压为2.3V的近红外发光电化学电池。
Sci Rep. 2019 Jan 18;9(1):228. doi: 10.1038/s41598-018-36420-1.
3
Efficient near infrared light emitting electrochemical cell (NIR-LEEC) based on new binuclear ruthenium phenanthroimidazole exhibiting desired charge carrier dynamics.
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RSC Adv. 2024 Jun 11;14(26):18646-18662. doi: 10.1039/d4ra02250e. eCollection 2024 Jun 6.
4
Pyrazolate-Bridged NHC Cyclometalated [Pt] Complexes and [PtAg(PPh)] Clusters in Electroluminescent Devices.用于电致发光器件的吡唑盐桥连的NHC环金属化[Pt]配合物和[PtAg(PPh)]簇合物
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5
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Sci Adv. 2024 Jan 5;10(1):eadj6583. doi: 10.1126/sciadv.adj6583.
6
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7
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9
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基于新型双核钌菲咯咪唑的高效近红外发光电化学电池(NIR-LEEC)展现出理想的电荷载流子动力学。
Sci Rep. 2017 Nov 16;7(1):15739. doi: 10.1038/s41598-017-16133-7.
4
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5
Simple light-emitting electrochemical cell using reduced graphene oxide and a ruthenium (II) complex.使用还原氧化石墨烯和钌(II)配合物的简易发光电化学电池。
Appl Opt. 2017 Aug 10;56(23):6476-6484. doi: 10.1364/AO.56.006476.
6
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Chem Commun (Camb). 2017 May 11;53(39):5457-5460. doi: 10.1039/c7cc01580a.
7
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8
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9
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Dalton Trans. 2016 Apr 25;45(17):7195-9. doi: 10.1039/c6dt00714g.