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行星条件下充满盐和气体的冰。

Salt- and gas-filled ices under planetary conditions.

作者信息

Bove Livia E, Ranieri Umbertoluca

机构信息

1 Dipartimento di Fisica, Universitá di Roma 'La Sapienza' , 00185 Roma , Italy.

2 Sorbonne Université, CNRS UMR 7590, IMPMC , 75005 Paris , France.

出版信息

Philos Trans A Math Phys Eng Sci. 2019 Jun 3;377(2146):20180262. doi: 10.1098/rsta.2018.0262.

Abstract

In recent years, evidence has emerged that solid water can contain substantial amounts of guest species, such as small gas molecules-in gas hydrate structures-or ions-in salty ice structures-and that these 'filled' ice structures can be stable under pressures of tens of Gigapascals and temperatures of hundreds of Kelvins. The inclusion of guest species can strongly modify the density, vibrational, diffusive and conductivity properties of ice under high pressure, and promote novel exotic properties. In this review, we discuss our experimental findings and molecular dynamics simulation results on the structures formed by salt- and gas-filled ices, their unusual properties, and the unexpected dynamical phenomena observed under pressure and temperature conditions relevant for planetary interiors modelling. This article is part of the theme issue 'The physics and chemistry of ice: scaffolding across scales, from the viability of life to the formation of planets'.

摘要

近年来,有证据表明固态水能够包含大量客体物种,例如气体水合物结构中的小分子气体或咸冰结构中的离子,并且这些“填充”的冰结构在数十吉帕斯卡的压力和数百开尔文的温度下能够保持稳定。客体物种的存在能够显著改变高压下冰的密度、振动、扩散和导电性质,并促进新的奇异性质的出现。在这篇综述中,我们讨论了关于盐填充冰和气填充冰所形成结构的实验发现和分子动力学模拟结果、它们的异常性质,以及在与行星内部建模相关的压力和温度条件下观察到的意外动力学现象。本文是主题为“冰的物理与化学:跨越尺度的框架,从生命的可行性到行星的形成”这一特刊的一部分。

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本文引用的文献

1
Filling Ices with Helium and the Formation of Helium Clathrate Hydrate.
J Phys Chem Lett. 2018 Jun 21;9(12):3194-3198. doi: 10.1021/acs.jpclett.8b01423. Epub 2018 Jun 1.
3
Calorimetric study of water's two glass transitions in the presence of LiCl.
Phys Chem Chem Phys. 2018 Feb 28;20(9):6401-6408. doi: 10.1039/c7cp08677f.
4
Fast methane diffusion at the interface of two clathrate structures.
Nat Commun. 2017 Oct 20;8(1):1076. doi: 10.1038/s41467-017-01167-2.
5
Topologically frustrated ionisation in a water-ammonia ice mixture.
Nat Commun. 2017 Oct 20;8(1):1065. doi: 10.1038/s41467-017-01132-z.
6
A Chiral Gas-Hydrate Structure Common to the Carbon Dioxide-Water and Hydrogen-Water Systems.
J Phys Chem Lett. 2017 Sep 7;8(17):4295-4299. doi: 10.1021/acs.jpclett.7b01787. Epub 2017 Aug 30.
7
Probing ice VII crystallization from amorphous NaCl-DO solutions at gigapascal pressures.
Phys Chem Chem Phys. 2017 Jan 18;19(3):1875-1883. doi: 10.1039/c6cp07340a.
10
Observation of Binding and Rotation of Methane and Hydrogen within a Functional Metal-Organic Framework.
J Am Chem Soc. 2016 Jul 27;138(29):9119-27. doi: 10.1021/jacs.6b01323. Epub 2016 Jul 13.

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