Liu Tong, Wang Xiao-Jun, Chen Qian, Wen Jie, Huang Bo, Zhu Hong-Xia, Tian Ying-Ze, Feng Yin-Chang
State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China.
Yantai Environmental Monitoring Center, Yantai 264003, China.
Huan Jing Ke Xue. 2019 Mar 8;40(3):1082-1090. doi: 10.13227/j.hjkx.201807252.
PM samples were collected at three sites in Yantai City during all four seasons of 2016-2017, and the mass concentration and chemical composition characteristics were analyzed. The CMB model was used to calculate source apportionment of ambient PM, and the backward trajectory cluster and PSCF were used to analyze the transport flow and potential source regions. The results showed that the average mass concentrations of PM in winter, spring, summer, and autumn in Yantai were (89.45±56.80), (76.78±28.44), (32.65±17.92) and (57.32±24.60) μg·m, respectively. The PM concentration showed a significant seasonal variation (<0.01). The contribution of PM sources was as follows:secondary nitrate (20.3%) > crustal dust (15.7%) > vehicle exhaust (14.9%) > coal combustion (13.8%) > secondary sulphate (12.8%) > SOC (6.1%) > cement dust (5.5%) > sea salt source (2.9%). It can be seen that the predominant sources were secondary sources, crustal dust, vehicle exhaust, and coal combustion. The sources of nitrate in spring and of crustal dust were important contributors. The contribution of sulfate in summer was prominent, and the proportion of coal combustion was high in autumn and winter. Yantai City's airflow transport and potential source regions also showed significant seasonal changes:winters were mainly affected by short-distance transport in Yantai City; summers were mainly affected by the coastal of eastern Yantai City and local areas; springs and autumns were mainly affected by regional transmission in the northeast and in the eastern coastal areas of Shandong Province and by local sources in Yantai City.
2016 - 2017年四季期间,在烟台市的三个地点采集了颗粒物(PM)样本,并分析了其质量浓度和化学成分特征。利用化学质量平衡(CMB)模型计算环境PM的源解析,利用后向轨迹聚类和潜在源贡献函数(PSCF)分析传输气流和潜在源区。结果表明,烟台市冬季、春季、夏季和秋季PM的平均质量浓度分别为(89.45±56.80)、(76.78±28.44)、(32.65±17.92)和(57.32±24.60)μg·m ,PM浓度呈现出显著的季节变化(<0.01)。PM源的贡献如下:二次硝酸盐(20.3%)>地壳尘(15.7%)>汽车尾气(14.9%)>煤炭燃烧(13.8%)>二次硫酸盐(12.8%)>有机碳(6.1%)>水泥粉尘(5.5%)>海盐源(2.9%)。可以看出,主要来源是二次源、地壳尘、汽车尾气和煤炭燃烧。春季硝酸盐源和地壳尘是重要贡献者。夏季硫酸盐的贡献突出,秋冬季节煤炭燃烧的比例较高。烟台市的气流传输和潜在源区也呈现出显著的季节变化:冬季主要受烟台市短途传输影响;夏季主要受烟台市东部沿海和局部地区影响;春秋季主要受山东省东北部和东部沿海地区的区域传输以及烟台市本地源影响。