由一对互补的同二位点主客体分子构成的超分子杯[4]吡咯聚合物。
Supramolecular calix[4]pyrrole polymers from a complementary pair of homoditopic host-guest molecules.
作者信息
Yuvayapan Samet, Aydogan Abdullah
机构信息
Department of Chemistry, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey.
出版信息
Chem Commun (Camb). 2019 Jul 23;55(60):8800-8803. doi: 10.1039/c9cc02806d.
PMID:31089591
Abstract
A triazole bridged bis-calix[4]pyrrole was successfully synthesized and further used for the first time to construct AABB type linear thermoresponsive supramolecular polymers by utilizing the host-guest interaction between calix[4]pyrroles and carboxylate units of tetrabutylammonium suberate.
摘要
成功合成了一种三唑桥连双杯[4]吡咯，并首次利用杯[4]吡咯与辛二酸四丁铵的羧酸盐单元之间的主客体相互作用，将其用于构建AABB型线性热响应超分子聚合物。
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