Quantum Interference in a Single Perovskite Nanocrystal.

Coherent manipulation of the exciton wave function in a single semiconductor colloidal nanocrystal (NC) has been actively pursued in the past decades without any success, mainly due to the bothersome existence of the spectral diffusion and the photoluminescence (PL) blinking effects. Such optical deficiencies can be naturally avoided in the newly developed colloidal NCs of perovskite CsPbI, leading to the PL spectrum with a stable intensity at the single-particle level. Meanwhile, from the first-order photon-correlation measurement, a PL line width smaller than 20 μeV is estimated for the emission state of the neutral exciton in a single CsPbI NC. Moreover, a dephasing time of about 10 ps can be extracted from the quantum interference measurement on the absorption state of the charged exciton. This stable demonstration of a coherent optical feature will advance single colloidal NCs into the quantum information regime, opening up an alternative yet prospective research direction beyond their traditional applications such as in optoelectronic devices and bioimaging.