Kaneko Masayoshi
Enzan Senior High School, 440-1, Enzanmikkaitiba, Koshu, Yamanashi, Japan.
Heliyon. 2019 May 18;5(5):e01734. doi: 10.1016/j.heliyon.2019.e01734. eCollection 2019 May.
Herein, anatase titanium dioxide (TiO) nanoparticles were prepared by boiling anatase TiO in water without using hydrothermal synthesis. This changed the particle diameter because boiling caused particle collision convection. Substrates were then prepared by assembling anatase nanoparticles on 3-aminopropyltrimethoxysilane (APTMS)-functionalized Al surfaces. The effect of pH on the preparation of anatase nanoparticles was investigated, with results indicating that pH 3 is optimal for anatase adsorption on Al surfaces. The anatase TiO suspension was thus adjusted to pH 3 using dilute HCl solution, and the Al surface selectively adsorbed anatase nanoparticles. This method enabled the adsorption of anatase TiO nanoparticles at room temperature, without using a heat source. In addition to Al substrates, this method was also found to be applicable to glass surfaces.
在此,通过在水中煮沸锐钛矿型二氧化钛(TiO₂)纳米颗粒而不使用水热合成法来制备纳米颗粒。这改变了粒径,因为煮沸导致颗粒碰撞和对流。然后通过将锐钛矿型纳米颗粒组装在3-氨丙基三甲氧基硅烷(APTMS)功能化的铝表面上来制备基底。研究了pH对锐钛矿型纳米颗粒制备的影响,结果表明pH 3对于锐钛矿型在铝表面的吸附是最佳的。因此,使用稀盐酸溶液将锐钛矿型TiO₂悬浮液调节至pH 3,铝表面选择性地吸附了锐钛矿型纳米颗粒。该方法能够在室温下吸附锐钛矿型TiO₂纳米颗粒,而无需使用热源。除了铝基底外,该方法还被发现适用于玻璃表面。