Ding Yitong, Li Xingwei, Zhao Ziru, Xiong Ying, Guo Shaoyun
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, 610065, China.
Sci Rep. 2019 Jun 17;9(1):8665. doi: 10.1038/s41598-019-45030-4.
Polycarbonate (PC)/Poly(styrene-co-acrylonitrile) (SAN)-organic silica bead (OSB) anisotropic light-scattering materials containing novel spindle-shaped core-shell particles through simple, low-cost hot stretching methods are prepared in situ, which have excellent and easily tunable optical properties. The effects of OSB particle size, OSB mass fraction and stretching ratio on the morphology of the spindle-shaped core-shell particles and the scattering properties of PC/SAN-OSB composites were studied in detail. The results show that smaller particle size OSB and smaller draw ratio are more conducive to the production of spindle-shaped core-shell particles. And because of the multiple scattering effects of the spindle-shaped core-shell particles, they have a significant compensation effect on the pattern short-axis light-scattering range of the PC anisotropic materials while ensuring that the pattern long-axis direction light-scattering range is not impaired.
通过简单、低成本的热拉伸方法原位制备了含有新型纺锤形核壳颗粒的聚碳酸酯(PC)/聚(苯乙烯 - 共 - 丙烯腈)(SAN)-有机硅珠(OSB)各向异性光散射材料,其具有优异且易于调节的光学性能。详细研究了OSB粒径、OSB质量分数和拉伸比对纺锤形核壳颗粒形态以及PC/SAN - OSB复合材料散射性能的影响。结果表明,较小粒径的OSB和较小的拉伸比更有利于纺锤形核壳颗粒的产生。并且由于纺锤形核壳颗粒的多重散射效应,它们在确保图案长轴方向光散射范围不受损的同时,对PC各向异性材料的图案短轴光散射范围有显著的补偿作用。