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具有嵌入式银纳米线的高灵敏度可拉伸聚氨酯纤维应变传感器。

Highly Sensitive and Stretchable Polyurethane Fiber Strain Sensors with Embedded Silver Nanowires.

作者信息

Zhu Guan-Jun, Ren Peng-Gang, Guo Han, Jin Yan-Ling, Yan Ding-Xiang, Li Zhong-Ming

机构信息

College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering , Sichuan University , Chengdu 610065 , China.

出版信息

ACS Appl Mater Interfaces. 2019 Jul 3;11(26):23649-23658. doi: 10.1021/acsami.9b08611. Epub 2019 Jun 19.

Abstract

Flexible strain sensors have attracted a great amount of attention for promising applications in next-generation artificially intelligent devices. However, it is difficult for conventional planar strain sensors to meet the requirements of miniature size and light weight for flexible electronics. Herein, a highly sensitive and stretchable fiber strain sensor with a millimeter diameter was innovatively fabricated by the capillary tube method to integrate silver nanowires (AgNWs) in polyurethane (PU) fibers. Scanning electron microscopy results demonstrate that AgNWs were embedded into the surface layer of PU fibers and formed completely conductive networks. The unique AgNW networks endow the PU/AgNW fibers with superior electrical conductivity of 3.1 S/cm, high elongation at break of 265%, wide response range of 43%, high gauge factor of 87.6 up to 22% strain, fast response time of 49 ms, and excellent reliability and stability. Such satisfactory stretchability and sensitivity is attributed to the combination of the highly stretchable PU matrix and the embedded architecture of the AgNW conductive network. Moreover, PU/AgNW fibers can be employed as wearable devices to detect various human motions and to drive light-emitting diodes at a lower voltage (2.7 V).

摘要

柔性应变传感器在下一代人工智能设备的潜在应用中已引起了极大关注。然而,传统的平面应变传感器难以满足柔性电子器件对微型化尺寸和轻量化的要求。在此,通过毛细管法创新性地制备了一种直径为毫米级的高灵敏度可拉伸纤维应变传感器,将银纳米线(AgNWs)集成到聚氨酯(PU)纤维中。扫描电子显微镜结果表明,AgNWs嵌入到PU纤维的表层并形成了完全导电网络。独特的AgNW网络赋予了PU/AgNW纤维3.1 S/cm的优异电导率、265%的高断裂伸长率、43%的宽响应范围、高达22%应变时87.6的高应变系数、49 ms的快速响应时间以及出色的可靠性和稳定性。如此令人满意的拉伸性和灵敏度归因于高可拉伸PU基体与AgNW导电网络的嵌入式结构的结合。此外,PU/AgNW纤维可用作可穿戴设备,以检测各种人体运动并在较低电压(2.7 V)下驱动发光二极管。

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