Esperança José M S S, Tariq Mohammad, Pereiro Ana B, Araújo João M M, Seddon Kenneth R, Rebelo Luis Paulo N
LAQV/REQUIMTE, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Caparica, Portugal.
QUILL Research Centre, the Queen's University of Belfast, Belfast, United Kingdom.
Front Chem. 2019 Jun 20;7:450. doi: 10.3389/fchem.2019.00450. eCollection 2019.
This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of C/V at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems.
本工作以简短综述的形式集中报道了离子液体及含离子液体体系出人意料且鲜为人知的响应。示例包括:(i) 某些离子液体等压热膨胀系数随温度变化出现极小值;(ii) 离子液体与分子溶剂二元混合物中的粘度极小值;(iii) 一类离子液体表面张力的异常现象;(iv) 室温及附近离子液体取代时C/V的恒定性;(v) 离子液体作为玻璃形成液体;(vi) 奇偶交替的侧烷基链长度效应;(vii) 离子液体及含离子液体体系中的绝对负压;(viii) 反电荷离子液体对;(ix) 离子液体 + 溶剂体系中的LCST不混溶行为。