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静电纺丝碳/CuO纳米复合材料作为锂离子电池可持续且高性能的阳极

Electrospun Carbon/Cu O Nanocomposite material as Sustainable and High Performance Anode for Lithium-Ion Batteries.

作者信息

Maroni Fabio, Bruni Pantaleone, Giuli Gabriele, Brutti S, Croce Fausto

机构信息

Dipartimento di Farmacia Università Degli Studi di Chieti-Pescara "G. D'Annunzio" Via Dei Vestini, 31 66100- Chieti.

Dipartimento di Scienze della Terra Università Degli Studi Di Camerino Via Gentile III da Varano, 27 62032- Camerino MC.

出版信息

ChemistryOpen. 2019 Jun 26;8(6):781-787. doi: 10.1002/open.201900174. eCollection 2019 Jun.

Abstract

The increase in energy density of the next generation of battery materials to meet the new challenges of the electrical vehicles era calls for innovative and easily scalable materials with sustainable processes. An innovative Cu O/C nanocomposite material, characterized by a highly conductive 3D-framework, with Cu O/Cu-metal contiguous nanodomains is prepared by electrospinning. The electrode processing is made using a polyacrylic acid binder. The nanocomposite has been fully characterized and the electrochemical performance shows high specific capacity values over 450 galvanostatic cycles at 500 mAg specific current with capacity retention values over 80 %. In addition, the composite shows remarkable high rate performance and highly stable interface, which has been studied by impedance spectroscopy.

摘要

为应对电动汽车时代的新挑战,下一代电池材料能量密度的提高需要具有可持续工艺的创新且易于扩展的材料。通过静电纺丝制备了一种创新的CuO/C纳米复合材料,其特征在于具有高导电性的3D框架以及CuO/Cu金属连续纳米域。电极加工使用聚丙烯酸粘合剂。对该纳米复合材料进行了全面表征,电化学性能表明,在500 mAg特定电流下经过450次恒电流循环,其比容量值较高,容量保持率超过80%。此外,通过阻抗谱研究表明,该复合材料具有显著的高倍率性能和高度稳定的界面。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fc15/6594352/d5269c422df2/OPEN-8-781-g001.jpg

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