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利用椰子油浸渍生物炭作为潜热储能隔热材料对生物复合材料进行表征。

Characterization of biocomposite using coconut oil impregnated biochar as latent heat storage insulation.

机构信息

Department of Architecture and Architectural Engineering, Yonsei University, Seoul 03722, Republic of Korea.

Korea Biochar Research Center, Division of Environmental Science and Ecological Engineering, Korea University, Seoul 02841, Republic of Korea.

出版信息

Chemosphere. 2019 Dec;236:124269. doi: 10.1016/j.chemosphere.2019.06.239. Epub 2019 Jul 1.

Abstract

Objective of this research was to characterize properties of the latent heat storage biocomposite (LHSBC) as a novel material that can be employed as a latent heat storage insulation by using biochar. Biochars produced from waste material pine cone, pine saw dust, and paper mill sludge were vacuum impregnated with a bio-based phase change material (PCM), coconut oil, to prepare LHSBCs. In particular, this paper analyzed the chemical stability, latent heat storage performance, thermal conductivity, and thermal stability of LHSBCs based on results of fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), laser flash method and thermogravimetric analysis (TGA). As a result, the LHSBCs showed a maximum latent heat storage capacity of 74.6 J/g and a low thermal conductivity of 0.030 W/mK at the maximum, confirming that LHSBCs have a high latent heat storage capacity and thermal insulation performance. With a maximum specific heat of 1.69 J/gK, a high, sensible heat storage was confirmed. In addition, all LHSBCs were found to be thermally and chemically stable. The LHSBC could be employed as a material with good thermal insulation performance and heat storage characteristics.

摘要

本研究的目的是通过使用生物炭来表征作为新型材料的潜热存储生物复合材料(LHSBC)的特性,该材料可以用作潜热存储隔热材料。从松球、松木锯末和造纸厂污泥等废料中制备的生物炭采用真空浸渍法用生物基相变材料(PCM)椰子油进行浸渍,以制备 LHSBC。具体来说,本文通过傅里叶变换红外光谱(FTIR)、差示扫描量热法(DSC)、激光闪光法和热重分析(TGA)分析了 LHSBC 的化学稳定性、潜热存储性能、导热系数和热稳定性。结果表明,LHSBC 的最大潜热存储容量为 74.6 J/g,最大导热系数为 0.030 W/mK,证实了 LHSBC 具有高的潜热存储容量和隔热性能。最大比热为 1.69 J/gK,证实了高的显热存储。此外,所有 LHSBC 均具有热稳定性和化学稳定性。LHSBC 可以用作具有良好隔热性能和蓄热特性的材料。

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