García Calvo José Luis, Sánchez Moreno Mercedes, Carballosa Pedro, Pedrosa Filipe, Tavares Fabiano
Eduardo Torroja Institute for Construction Sciences, Consejo Superior de Investigaciones Científicas (CSIC), Serrano Galvache, 4, 28033 Madrid, Spain.
Department of Inorganic Chemistry and Chemical Engineering, University of Córdoba (UCO), Campus de Rabanales, 14071 Córdoba, Spain.
Materials (Basel). 2019 Jul 26;12(15):2384. doi: 10.3390/ma12152384.
Crystalline hydrophilic additives are increasingly used as efficient methods for reducing water permeability in concrete. Their effectiveness in hindering water penetration has been proven in different cementitious materials, although scarce information has been reported concerning their action mechanism. In the present work, the efficacy of a hydrophilic blended crystalline mix (Krystaline Add1) as a water-reducing additive has been confirmed. Furthermore, an extended study about how the presence of the additive influences both the fresh state and the hardened state properties is presented. Finally, characterization techniques such as Mercury Intrusion Porosimetry (MIP), X-ray Powder Diffraction (XRD) and Back-Scattered Scanning Electron Microscopy (BSEM) with Energy Dispersive X-ray analysis (EDAX) have been used for deducing the mechanism of the additive. No significant deleterious influence on the concrete properties due to the addition of the additive has been detected. In fact, the additive seems to have provided a positive influence on the concrete given that a slight reduction in the w/c ratio for similar consistency has been detected, with the subsequent improvement of the compressive strength values. Its effectiveness as a water permeability reducing additive has shown encouraging results having reduced the water permeability by approximately 50% during testing. The action mechanism of the studied additive seems to be related to hydration reactions in the presence of water, producing new solid amorphous phases in the concrete bulk.
结晶型亲水性添加剂越来越多地被用作降低混凝土透水性的有效方法。它们在阻碍水分渗透方面的有效性已在不同的胶凝材料中得到证实,尽管关于其作用机理的报道很少。在本研究中,已证实一种亲水性混合结晶混合物(Krystaline Add1)作为减水添加剂的功效。此外,还对添加剂的存在如何影响新拌状态和硬化状态性能进行了深入研究。最后,采用了诸如压汞法(MIP)、X射线粉末衍射(XRD)以及带有能谱分析(EDAX)的背散射扫描电子显微镜(BSEM)等表征技术来推导添加剂的作用机理。未检测到由于添加该添加剂而对混凝土性能产生的明显有害影响。事实上,该添加剂似乎对混凝土产生了积极影响,因为在相似稠度下检测到水灰比略有降低,随后抗压强度值有所提高。其作为降低透水性添加剂的有效性已显示出令人鼓舞的结果,在测试期间透水性降低了约50%。所研究添加剂的作用机理似乎与有水存在时的水化反应有关,在混凝土基体中产生新的固体非晶相。