Kondo Toshiki, Muta Hiroaki, Kurosaki Ken, Kargl Florian, Yamaji Akifumi, Furuya Masahiro, Ohishi Yuji
Graduate School of Engineering, Osaka University, Japan.
Institut für Materialphysik im Weltraum, Deutsches Zentrum für Luft - und Raumfahrt (DLR), 51170, Köln, Germany.
Heliyon. 2019 Jul 22;5(7):e02049. doi: 10.1016/j.heliyon.2019.e02049. eCollection 2019 Jul.
Liquid ZrO is one of the most important materials involved in severe accident analysis of a light-water reactor. Despite its importance, the physical properties of liquid ZrO are scarcely reported. In particular, there are no experimental reports on the viscosity of liquid ZrO. This is mainly due to the technical difficulties involved in the measurement of thermo-physical properties of liquid ZrO, which has an extremely high melting point. To address this problem, an aerodynamic levitation technique was used in this study. The density of liquid ZrO was calculated from its mass and volume, estimated based on the recorded image of the sample. The viscosity was measured by a droplet oscillation technique. The density and viscosity of liquid ZrO at temperatures ranging from 2753 K to 3273 K, and 3170 K-3471 K, respectively, were successfully evaluated. The density of liquid ZrO was found to be 4.7 g/cm at its melting point of 2988 K and decreased linearly with increasing temperature, and the viscosity of liquid ZrO was 13 mPa at its melting point.
液态ZrO是轻水反应堆严重事故分析中最重要的材料之一。尽管其很重要,但液态ZrO的物理性质鲜有报道。特别是,关于液态ZrO的粘度尚无实验报告。这主要是由于测量液态ZrO热物理性质存在技术困难,因为其熔点极高。为解决这一问题,本研究采用了气动悬浮技术。液态ZrO的密度根据其质量和体积计算得出,体积基于记录的样品图像估算。粘度通过液滴振荡技术测量。分别成功评估了2753 K至3273 K以及3170 K至3471 K温度范围内液态ZrO的密度和粘度。发现液态ZrO在其熔点2988 K时密度为4.7 g/cm³,并随温度升高呈线性下降,液态ZrO在其熔点时粘度为13 mPa。