阳离子-π 诱导的锂离子掺杂共轭微孔聚合物，具有显著的储氢性能。
Cation-π induced lithium-doped conjugated microporous polymer with remarkable hydrogen storage performance.
机构信息
State Key Laboratory of Environment-friendly Energy Materials & School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, 621010, P. R. China.
出版信息
Chem Commun (Camb). 2019 Sep 17;55(75):11227-11230. doi: 10.1039/c9cc04174e.
PMID:31469129
Abstract
A cation-π induced lithium-doped conjugated microporous polymer, Li+-PTAT, was constructed. It was proved that the point to face cation-π interactions between Li+ and indole can endow the resulting Li+-PTAT with high Li+ content and without agglomeration, which further leads to its encouraging hydrogen storage capacity.
摘要
一种阳离子-π 诱导的锂掺杂共轭微孔聚合物 Li+-PTAT 被构建。证明了 Li+和吲哚之间的点对面阳离子-π 相互作用可以赋予所得 Li+-PTAT 高的锂离子含量且不会发生团聚，这进一步导致其具有令人鼓舞的储氢能力。
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