Department of Food Science , ARO Volcani Center , Bet Dagan 50250 , Israel.
Institute of Biochemistry, Food Science and Nutrition, Faculty of Agriculture Food and Environment , The Hebrew University of Jerusalem , Rehovot 76100 , Israel.
J Agric Food Chem. 2019 Oct 2;67(39):10930-10936. doi: 10.1021/acs.jafc.9b03741. Epub 2019 Sep 20.
The stability of lipids in meat products depends on the initial concentration of hydroperoxides, the catalytic involvement of metal ions and myoglobin, endogenous antioxidants, and biological and technological factors. Ground meat was treated with additives, sealed in vacuum bags, heated to 75 °C, and stored opened to air at 4 °C. -Nitroso--acetylcysteine (NAC-SNO) at concentration like nitrite used by the industry prevents lipid peroxidation in the product, even after storage for 1 month at 4 °C. The same simulated treatments at different concentrations of both compounds show that NAC-SNO acts as an antioxidant ∼4-fold better than nitrite at pH 6.2 or 3.0. Ascorbic acid significantly improves nitrite antioxidant effect. NAC-SNO was found to prevent, much better than nitrite, accumulation of reactive aldehydes and hydroxynonenal protein modification. In condition like those used by the industry for meat products processing, NAC-SNO acts better than nitrite to provide antioxidant protection without the side effect of -nitrosation, oxidation, and the loss of nutrient generated by nitrite.
肉品中脂质的稳定性取决于氢过氧化物的初始浓度、金属离子和肌红蛋白的催化作用、内源性抗氧化剂以及生物和技术因素。将绞碎的肉用添加剂处理,密封在真空袋中,加热至 75°C,并在 4°C 下打开空气储存。-亚硝基--乙酰半胱氨酸(NAC-SNO)的浓度与行业中使用的亚硝酸盐相当,可以防止产品中的脂质过氧化,即使在 4°C 下储存 1 个月后也是如此。在不同浓度的两种化合物下进行相同的模拟处理表明,NAC-SNO 在 pH 值为 6.2 或 3.0 时的抗氧化活性比亚硝酸盐高约 4 倍。抗坏血酸显著提高了亚硝酸盐的抗氧化效果。研究发现,NAC-SNO 可以防止反应性醛和羟壬烯醛的积累以及蛋白质修饰,其效果远优于亚硝酸盐。在用于肉类加工的工业条件下,NAC-SNO 的抗氧化保护作用优于亚硝酸盐,而不会产生亚硝化、氧化和亚硝酸盐导致的营养素损失等副作用。