Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing, 210096, China.
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing, 210096, China.
Chemosphere. 2020 Feb;240:124853. doi: 10.1016/j.chemosphere.2019.124853. Epub 2019 Sep 19.
Co-combustion of coal and wheat straw (WS) was conducted in a lab-scale BFB combustor. Fuel composition (coal, 70%coal+30%WS), temperature (750, 800, 850, 900, 950 °C), secondary air ratio (0, 10%, 20%, 30%) were varied to on the release of gaseous pollutant was studied. CO, NO and SO concentration in flue gas (FG) were measured on-line by a flue gas analyzer. Fly ash (FA), bottom slag (BS) and bed material (BM) were collected, digested and analyzed by ICP-OES to determine the distribution of heavy metals (e.g. Pb, Zn, Cr and Cd). Results indicated that co-combustion could improve the combustion of coal alone by reducing CO, NO and SO emission and carbon content in fly ash effectively. In co-combustion the increasing secondary air could reduce CO emission and SO by enhancing disturbance and promoting sulfation respectively while the minimum NO emission was reached at the ratio of 20%. Co-combustion restrained the release of Zn, Cd and Pb compared with coal combustion alone. In co-combustion, high temperature increased their portion in the flue gas. For Zn, Pb and Cd, their content in the bottom solids increased while the portion of Cr decreased. Secondary air decreased their content in fly ash and transferred into flue gas significantly and in bottom solids content of Zn and Pb decreased while Cd increased.
在实验室规模的鼓泡流化床燃烧器中进行了煤与小麦秸秆(WS)的共燃烧实验。改变燃料组成(煤,70%煤+30%WS)、温度(750、800、850、900、950°C)和二次空气比(0、10%、20%、30%),研究了气态污染物的释放情况。通过烟气分析仪在线测量了烟气(FG)中的 CO、NO 和 SO 浓度。收集、消化和分析了飞灰(FA)、底渣(BS)和床料(BM),通过 ICP-OES 确定了重金属(如 Pb、Zn、Cr 和 Cd)的分布。结果表明,共燃烧可以通过有效降低 CO、NO 和 SO 的排放以及飞灰中的碳含量来改善煤的单独燃烧。在共燃烧中,增加二次空气可以通过增强干扰和促进硫化分别降低 CO 排放和 SO,而达到最小 NO 排放的比例为 20%。与煤单独燃烧相比,共燃烧可以抑制 Zn、Cd 和 Pb 的释放。在共燃烧中,高温增加了它们在烟气中的比例。对于 Zn、Pb 和 Cd,它们在底渣中的含量增加,而 Cr 的含量减少。二次空气显著降低了它们在飞灰中的含量,并将其转移到烟气中,Zn 和 Pb 的底渣含量降低,而 Cd 的含量增加。