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一种自组装的、珍珠层仿生的纳米层状结构,作为用于 HVDC 气体绝缘系统的绝缘子的优异电荷耗散涂层。

A self-assembled, nacre-mimetic, nano-laminar structure as a superior charge dissipation coating on insulators for HVDC gas-insulated systems.

机构信息

State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi'an Jiaotong University, Xi'an 710049, China.

出版信息

Nanoscale. 2019 Oct 10;11(39):18046-18051. doi: 10.1039/c9nr06827a.

Abstract

Nacre is well-known for its unique properties due to its "bricks-and-mortar" structure. We employed this biological paradigm to fabricate nano-laminar coatings with controlled arrangement of montmorillonite (MMT) nanoclay sheets and polyvinyl alcohol (PVA) polymer binders by a self-assembly process. The abundant inorganic/organic interfaces were demonstrated to play critical roles in enhancing charge dissipation laterally on the insulator surface, so that the surface charge accumulation is suppressed under dc stress. Moreover, the stacking barriers help to protect insulator surfaces from hot electron bombardment, inhibiting further electron avalanche. In this manner, the flashover strength of the insulator is improved by 18%. This strategy is practical and scalable, allowing for industrial applications.

摘要

珍珠母以其独特的“砖-泥”结构而闻名。我们采用这种生物范例,通过自组装工艺制备了具有可控蒙脱土(MMT)纳米粘土片和聚乙烯醇(PVA)聚合物粘合剂排列的纳米层状涂层。丰富的无机/有机界面被证明在增强绝缘体表面横向电荷耗散方面起着关键作用,从而抑制直流应力下的表面电荷积累。此外,堆叠势垒有助于保护绝缘体表面免受热电子轰击,抑制进一步的电子雪崩。通过这种方式,提高了绝缘体的闪络强度 18%。该策略具有实用性和可扩展性,适用于工业应用。

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