含中心>E-E'<键（E、E'=P、SiH）的双-[3]二茂铁并苯：制备、性质及热活化
Bis-[3]Ferrocenophanes with Central >E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation.
作者信息
Isenberg Stefan, Weller Stefan, Kargin Denis, Valić Srećko, Schwederski Brigitte, Kelemen Zsolt, Bruhn Clemens, Krekić Kristijan, Maurer Martin, Feil Christoph M, Nieger Martin, Gudat Dietrich, Nyulászi László, Pietschnig Rudolf
机构信息
Institute for Chemistry and CINSaT University of Kassel Heinrich Plett-Straße 40 34132 Kassel Germany.
Institute for Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70550 Stuttgart Germany.
出版信息
ChemistryOpen. 2019 Jun 26;8(10):1235-1243. doi: 10.1002/open.201900182. eCollection 2019 Oct.
A series of bis-[3]ferrocenophanes of the general type Fe(CHE')E-E(E'CH)Fe (E=P, SiH and E'=PBu, NPentyl, NSi(CH)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
已经制备了一系列具有等瓣分子骨架的通式为Fe(CHE')E-E(E'CH)Fe（E = P、SiH，E' = PBu、NPentyl、NSi(CH)）的双-[3]二茂铁基化合物，并通过异核核磁共振光谱和X射线晶体学对其进行了表征。使用电子顺磁共振光谱和量子化学计算研究了关于中心键均裂生成磷中心自由基的热解离行为。
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