关于 1-氨基-2-硝基胍（ANQ）反应性的综述。

A Review on the Reactivity of 1-Amino-2-Nitroguanidine (ANQ).

机构信息

School of Chemical Engineering, Northwest University, Xi'an 710069, China.

Xi'an Modern Chemistry Research Institute, Xi'an 710065, China.

出版信息

Molecules. 2019 Oct 8;24(19):3616. doi: 10.3390/molecules24193616.

DOI:10.3390/molecules24193616

PMID:31597251

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6804259/

Abstract

1-Amino-2-nitroguanidine (ANQ) is a high-energy nitrogen-rich compound with good detonation properties and low sensitivities. ANQ has only a central carbon atom with three small groups around it, including an amino, a hydrazine and a nitroxyl group. Though the molecular structure of ANQ is very simple, its reactivity is surprisingly abundant. ANQ can undergo various reactions, including reduction reaction, acylation reaction, salification reaction, coordination reaction, aldimine condensation reaction, cyclization reaction and azide reaction. Many new energetic compounds were purposely obtained through these reactions. These reactions were systematically summarized in this review, and detonation properties of some energetic compounds were compared. In the field of energetic materials, ANQ and some derivatives exhibit good application prospects.

摘要

1-氨基-2-硝胍（ANQ）是一种高能含氮化合物，具有良好的爆炸性能和低敏感性。ANQ 只有一个中心碳原子，周围有三个小基团，包括一个氨基、一个肼基和一个硝肟基。尽管 ANQ 的分子结构非常简单，但它的反应性却非常丰富。ANQ 可以进行各种反应，包括还原反应、酰化反应、成盐反应、配位反应、缩醛缩胺反应、环化反应和叠氮反应。许多新型含能化合物都是通过这些反应有意获得的。本文对这些反应进行了系统总结，并比较了一些含能化合物的爆轰性能。在含能材料领域，ANQ 及其衍生物具有良好的应用前景。