Tarrés Quim, Oliver-Ortega Helena, Espinach F Xavier, Mutjé Pere, Delgado-Aguilar Marc, Méndez José A
LEPAMAP Group, Department of Chemical Engineering, University of Girona, Girona 17003, Spain.
Càtedra de Processos Industrials Sostenibles, University of Girona, Girona 17003, Spain.
Polymers (Basel). 2019 Oct 23;11(11):1736. doi: 10.3390/polym11111736.
This paper is focused on the flexural properties of bleached kraft softwood fibers, bio-based, biodegradable, and a globally available reinforcement commonly used in papermaking, of reinforced polylactic acid (PLA) composites. The matrix, polylactic acid, is also a bio-based and biodegradable polymer. Flexural properties of composites incorporating percentages of reinforcement ranging from 15 to 30 wt % were measured and discussed. Another objective was to evaluate the strength of the interface between the matrix and the reinforcements, using the rule of mixtures to determine the coupling factor. Nonetheless, this rule of mixtures presents two unknowns, the coupling factor and the intrinsic flexural strength of the reinforcement. Hence, applying a ratio between the tensile and flexural intrinsic strengths and a defined fiber tensile and flexural strength factors, derived from the rule of mixtures is proposed. The literature lacks a precise evaluation of the intrinsic tensile strength of the reinforcements. In order to obtain such intrinsic tensile strength, we used the Kelly and Tyson modified equation as well as the solution provided by Bowyer and Bader. Finally, we were able to characterize the intrinsic flexural strengths of the fibers when used as reinforcement of polylactic acid.
本文聚焦于漂白硫酸盐针叶木纤维的弯曲性能,这种纤维是生物基、可生物降解且在造纸中常用的全球通用增强材料,用于增强聚乳酸(PLA)复合材料。基体聚乳酸也是一种生物基且可生物降解的聚合物。对含有15%至30%重量百分比增强材料的复合材料的弯曲性能进行了测量和讨论。另一个目标是利用混合法则确定耦合因子,以评估基体与增强材料之间界面的强度。然而,这种混合法则存在两个未知数,即耦合因子和增强材料的固有弯曲强度。因此,建议应用拉伸强度与弯曲强度之比以及从混合法则推导得出的定义纤维拉伸强度和弯曲强度因子。文献中缺乏对增强材料固有拉伸强度的精确评估。为了获得这种固有拉伸强度,我们使用了凯利和泰森修正方程以及鲍耶尔和巴德提供的解决方案。最后,我们能够表征纤维用作聚乳酸增强材料时的固有弯曲强度。