电生成的Sm(II)催化的CO活化用于苄基卤化物的羧化反应
Electrogenerated Sm(II)-Catalyzed CO Activation for Carboxylation of Benzyl Halides.
作者信息
Bazzi Sakna, Schulz Emmanuelle, Mellah Mohamed
机构信息
Institut de Chimie Moléculaire et des Matériaux d'Orsay (UMR CNRS 8182), Equipe Catalyse Moléculaire , Université Paris Sud, Université Paris-Saclay , 15, rue Georges Clémenceau , 91405 Orsay , Cedex, France.
出版信息
Org Lett. 2019 Dec 20;21(24):10033-10037. doi: 10.1021/acs.orglett.9b03927. Epub 2019 Dec 6.
Sm(II)-catalyzed carboxylation of benzyl halides is reported through the electrochemical reduction of CO. The transformation proceeds under mild reaction conditions to afford the corresponding phenylacetic acids in good to excellent yields. This user-friendly and operationally simple protocol represents an alternative to traditional strategies, which usually proceeds through the C(sp)-halide activation pathway.
据报道，通过一氧化碳的电化学还原实现了钐（II）催化的苄基卤化物的羧化反应。该转化反应在温和的反应条件下进行，能以良好至优异的产率得到相应的苯乙酸。这种用户友好且操作简单的方法是传统策略的一种替代方案，传统策略通常通过碳（sp）-卤化物活化途径进行。
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